<![CDATA[ABSTRACT. This study aims to improve the efficiency of dye-sensitized solar cells (DSSCs). To overcome the recombination problem in the commonly used TiO2 semiconductor, we performed electrodeposition of ferrous metal (Fe) on TiO2. XRD characterization showed that after Fe electrodeposition, the crystal structure of TiO₂ remained in the anatase phase without significant changes compared to before deposition while based on SEM-EDS results, Fe was dispersed to form small agglomerates that functioned as metal contacts to reduce electron recombination. We also investigated the use of anthocyanins from various natural sources, including jengkol skin, senduduk fruit, mangosteen skin, and red grape skin. These anthocyanins were copigmented with salicylic acid. UV-Vis spectroscopy revealed that copigmentation caused a bathochromic shift and FTIR spectrum confirmed strong interaction between anthocyanins and salicylic acid through hydrogen bond formation. The combination of TiO2-Fe layers with pigmented dyes resulted in diverse DSSC efficiencies, with mangosteen peel showing the best performance (4.123%), followed by senduduk fruit (3.495%), grape peel (2.569%), and jengkol peel (1.925%). The increase in efficiency from 1.189% (without Fe coating) to 1.700% (with Fe coating) demonstrates the potential of this technique. The small TiO2 crystal size (about 61.8 nm) also contributes to the increased surface area, enhancing dye absorption and solar cell performance. The electrical efficiency showed that the combination of TiO2-Fe with copigmented anthocyanins from mangosteen skin produced DSSCs with the highest efficiency, demonstrating the potential of this approach to improve the performance of natural dye-based solar cells. Keywords: Co-pigmentation, dye-sensitized solar cell, Fe electroplating, natural dye.]]>
