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COMPARATIVE OF INHIBITORY EFFICIENCY OF LIGNIN EXTRACT OF NIPAH (Nypa fruticans Wurmb) PEEL AND FROND ON MILD STEEL IN HCl MEDIUM Emriadi, Emriadi; Sartika, Hilda; Pradiwi, Nailatul Zahrah; Stiadi, Yeni
Indonesian Journal of Pure and Applied Chemistry Vol 8, No 1 (2025)
Publisher : Tanjungpura University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26418/indonesian.v8i1.83186

Abstract

Lignin extract from nipah fruit skin and nipah frond (Nypa fruticans Wurmb) was effectively extracted and used as a corrosion inhibitor on mild steel samples. The corrosion inhibition efficiency of lignin extract in 1 N HCl solution was determined by the weight loss method and surface morphology analysis using an optical microscope. The measurement results showed that the highest efficiency was obtained at the concentration of lignin extract from fruit skin (ELBN) and nipah frond (ELPN) of 82.16 and 78.36%. The adsorption of lignin extract on the surface of mild steel follows the Langmuir isotherm adsorption and includes mixed adsorption leading to chemical adsorption.
Sifat Adsorptif dan Termodinamika Ekstrak Lignin dari Pelepah Nipah (Nypa fruticans Wurmb) untuk Korosi Baja Lunak dalam Medium HCl Sartika, Hilda; Emriadi; Stiadi, Yeni; Suryati, Suryati
Jurnal Fisika Unand Vol 13 No 6 (2024)
Publisher : Universitas Andalas

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.25077/jfu.13.6.784-791.2024

Abstract

Research on the adsorptive and thermodynamic properties of lignin extract from Nipah fronds (Nypa fruticans Wurmb) for mild steel corrosion in hydrochloric acid medium has been conducted. The inhibititon effect of lignin extract from Nipah (Nypa fruticans Wurmb) fronds (LENF) on the corrosion of mild steel in HCl solution was studied by weight loss and optical microscopy methods. The results show that LENF was a good inhibitor in 1.0 M HCl, and the inhibition efficiency increases with increasing concentration of the extract and temperature. Inhibitive effect was afforded by the adsorption of the extract on the steel surface, which was found to accord with Langmuir adsorption isotherm. Adsorption and activation parameters such as activation energy (Ea), enthalpy (∆Η), free Gibbs energy (∆G), and entropy (∆S) were evaluated on the corrosion and inhibition process.