Wardana, Afif
Unknown Affiliation

Published : 2 Documents Claim Missing Document
Claim Missing Document
Check
Articles

Found 2 Documents
Search

Characteristics of Carbonaceous Materials Synthesized from Palm Oil Empty Fruit Bunch Waste Using Ferrocene Catalyst Shahab, Ahmad Nabil; Islam, Adinda Izzatul; Wardana, Afif; Yahya, Ilham Nur Dimas; Amalia, Ary Yanuar Tri; Sofyan, Nofrijon; Dhaneswara, Donanta
Journal of Materials Exploration and Findings Vol. 4, No. 1
Publisher : UI Scholars Hub

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

The synthesis of carbonaceous materials for reduced graphene oxide (rGO) precursors using oil palm empty fruit bunches waste as a carbon source offers a sustainable solution for waste management in the palm oil industry while delivering high-performance materials. The oil palm empty fruit bunches were carbonized, followed by acid washing, pyrolysis with ferrocene (8%, 12%, and 16% variations), and ultrasonication to produce rGO. The structural, electronic, and morphological properties of the rGO were analyzed using various characterization techniques. The band gap values decreased with increasing ferrocene concentration, from 1.14 eV (8%) to 1.06 (16%), indicating enhanced electronic conductivity. XRD analysis revealed a crystal size increase from 11.3 nm (8%) to 181 nm (16%), while Raman spectroscopy showed a consistent D to G intensity ratio of 0.85, indicating reduced structural defects. SEM-EDS results demonstrated a carbon to oxygen atomic ratio of 4.38 (8%), 3.79 (12%), and 3.77 (16%), confirming successful reduction and improved carbon content. These finding highlight the potential of rGO synthesized from oil palm empty fruit bunches for applications in semiconductors, energy storage, and gas sensing, offering an innovative approach to sustainable materials development.
An Overview of Biomass-Derived Graphene Oxide and Its Characteristics for Future Sustainable Applications Wardana, Afif; Shahab, Ahmad Nabil; Dhaneswara, Donanta; Sofyan, Nofrijon
Journal of Materials Exploration and Findings Vol. 4, No. 3
Publisher : UI Scholars Hub

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

The production of graphene oxide (GO) from biomass presents considerable promise as a sustainable alternative substitute for traditional semiconductors. Biomass waste, abundant and often underutilized worldwide, is distinguished by its high carbon content and regenerative characteristics, rendering it an optimal resource for sustainable material production. By heating its biopolymers, lignocellulosic biomass can be used as a new material to make graphene, which forms three-dimensional turbostratic crystallites. These crystallites, composed of partially defective aromatic carbon sheets with graphite-like characteristics, make it easier to create GO with specialized functions for cutting-edge applications. Its capability underscores the revolutionary potential of biomass waste in producing high-value products from otherwise overlooked resources . A number of manufacturing methods are carefully studied and tested to improve the structure and oxygen functionality of GO. These include catalytic ferrocene, Hummer's, modified Hummer's, catalytic acid spray (CAS), Tour's, and electrochemical exfoliation. Additionally, doping with non-metallic elements, including nitrogen, boron, sulfur, and phosphorus (e.g., N, B, S, P), is investigated to adjust the band gap and improve charge carrier mobility, all of which are essential for optimizing electro-optical performance in semiconductors. This study highlights the unexploited potential of biomass as a resource and establishes a foundation for the advancement of GO-based semiconductors, driving the development of more environmentally friendly, efficient, and sustainable electronic technology.