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Sultan Napoleon
Department of Chemistry, The Republic of Indonesia Defense University, Kawasan IPSC Sentul, Bogor 16810, Indonesia
Chemical Engineering, Chemistry & Bioengineering Chemistry Materials Science & Nanotechnology

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Adsorption Ni(II) on Magnetic Fulvic Acid-Chitosan: Kinetics and Isotherm Study Raihansyah Raja Hutama; Audrey Nur Aisyah; Azzahra Sandri; Mayang Fauziah Putri Kuntjahjono; Sultan Napoleon; Yusuf Bramastya Apriliyanto; Nugroho Adi Sasongko; Rahmat Basuki
Sorption Studies Vol. 1 No. 1 (2025): Sorption Studies, Vol. 1 No. 1 June 2025
Publisher : Indonesian Scholar Society

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.55749/ss.v1i1.79

Abstract

Indonesia, as one of the most populous countries in the world, requires clean water sources. Industrial waste that is improperly discharged pollutes water bodies with hazardous metals. Adsorption is one of the effective methods for reducing the concentration of harmful metals in water. This study utilized fulvic acid extracted from goat manure compost and combined it with chitosan and magnetite as an adsorbent material for Ni(II). The FTIR results for the magnetite-fulvic acid-chitosan composite showed a peak at 1627 cm⁻¹, indicating the presence of aromatic C=C, aromatic ring -OH, and quinone C=O groups, which confirm the binding of fulvic acid. BET analysis was performed on magnetite and magnetite-fulvic acid-chitosan, and the pore volume and pore size were found to be 0.177488 cm³/g and 6.5394 nm, respectively. The composite exhibited magnetic behavior due to the attraction between the magnetite-fulvic acid-chitosan and an external magnet. Adsorption tests using isotherm and kinetic models revealed that Ni(II) adsorption followed a multilayer mechanism and pseudo-second-order kinetics, with a b value of 121.68 mg/g and an experimental qe of 6.28 × 10⁻⁵ mol/g. This shows that the magnetite-fulvic acid-chitosan composite is a promising, sustainable, and magnetically separable adsorbent for the effective removal of nickel ions from contaminated water.
Synthesis of Magnetite/Chitin/Fulvic Acid Derived from Goat Manure Compost and Adsorption Study of Zn(II) for Water Security Enhancement Audrey Nur Aisyah; Azzahra Sandri; Raihansyah Raja Hutama; Mayang Fauziah Putri Kuntjahjono; Sultan Napoleon; Rahmat Basuki
Sorption Studies Vol. 1 No. 1 (2025): Sorption Studies, Vol. 1 No. 1 June 2025
Publisher : Indonesian Scholar Society

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.55749/ss.v1i1.82

Abstract

Water pollution due to heavy metals such as Zn(II) poses a risk to the environment and health. This study aims to synthesize Magnetite/Chitin/Fulvic Acid (AF)-based composite adsorbent from goat feces compost and evaluate its effectiveness in adsorbing Zn(II) ions. Fulvic acid was extracted through alkaline-acid method and synthesized together with chitin and magnetite using one pot coprecipitation method. Characterization using FTIR, XRD, and BET showed successful synthesis with mesoporous structure for BET (average pore size 6.15 nm, surface area 41.77 m²/g). Isotherm studies showed that the adsorption of Zn(II) showed a good fit with the Freundlich (R² = 0.9967) and Temkin (R² = 0.9968) models, indicating multilayer adsorption on the heterogeneous surface. The composite also shows good adsorption ability and can be magnetically separated, making it an environmentally friendly and efficient potential adsorbent for wastewater treatment applications.
Effect of Different Temperatures in Magnetite Synthesis on Methylene Blue Adsorption Dea Dwi Ananda; Sultan Napoleon; Thessa Octavia Joyetta Tarigan; Tiara Rizki Yulita; Latisa Stefi Alivia; Bagas Kusuma; M. Rizki Fajri; Kayla Sophia Putri; Nayantaka Virsa Artdero; Nurwanto; Rudi Hartono; Rahmat Basuki
Sorption Studies Vol. 1 No. 2 (2025): Sorption Studies, December 2025
Publisher : Indonesian Scholar Society

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.55749/ss.v1i2.84

Abstract

This study aims to synthesize magnetite (Fe₃O₄) particles using the coprecipitation method, with variations in temperature (70°C and 90°C) and reaction system (open and closed) to evaluate their effects on product quality. Characterization was conducted using FTIR, XRD, and organoleptic observation to confirm the formation of Fe₃O₄. Additional tests included magnetic attraction measurements through mass response and adsorption capacity (Q) analysis using methylene blue. FTIR analysis showed absorption bands at 3417.00 cm⁻¹, 1627 cm⁻¹, 1404 cm⁻¹, and 578 cm⁻¹, indicating the presence of O–H, C=O, and Fe–O functional groups. XRD patterns revealed diffraction peaks at 2θ values of 30.27°, 35.23°, 43.22°, 53.71°, 57.43°, and 62.11°, confirming the spinel crystal structure of Fe₃O₄. The sample synthesized at 90°C under closed conditions exhibited a darker black color and higher mass yield, suggesting improved crystallinity and phase purity. The closed system also showed higher adsorption capacities of 0.0008 mmol·g⁻¹ at 70°C and 0.0018 mmol·g⁻¹ at 90°C, along with stronger magnetic response. The open system produced a black precipitate with lower yield and weaker magnetic response, suggesting oxidation of Fe²⁺ to Fe³⁺ due to direct contact with oxygen, leading to the formation of compounds such as hematite or maghemite with lower magnetic properties. These results confirm that higher reaction temperatures and closed conditions optimally enhance the quality and stability of magnetite.
Co-Authors Audrey Nur Aisyah Azzahra Sandri Bagas Kusuma Dea Dwi Ananda Kayla Sophia Putri Latisa Stefi Alivia M. Rizki Fajri Mayang Fauziah Putri Kuntjahjono Nayantaka Virsa Artdero Nugroho Adi Sasongko Nurwanto Rahmat Basuki Raihansyah Raja Hutama Rudi Hartono Thessa Octavia Joyetta Tarigan Tiara Rizki Yulita Yusuf Bramastya Apriliyanto