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Effect of Column Diameter on the Performance of an Ion Exchange System in Reducing Water Hardness Rawati, Widya Yeni; Sunardi; Widarti, Sri; Sumarja; Nur Alim, Muhammad
KOVALEN: Jurnal Riset Kimia Vol. 11 No. 2 (2025): December Edition
Publisher : Chemistry Department, Mathematics and Natural Science Faculty, Tadulako University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22487/kovalen.2025.v11.i2.17907

Abstract

Ion exchange is an effective method for removing hardness ions such as Ca2+ and Mg2+ from water, and its performance is strongly influenced by column design parameters. This study aims to evaluate the effect of column diameter on the efficiency of a sequentially operated cation–anion ion exchange system at a constant flow rate of 10 L/h. Six column diameters (20, 25, 30, 35, 40, and 50 mm) were tested using synthetic solutions. The results showed that the 30 mm column achieved the highest ion-exchange performance, with a removal efficiency of 92.47%. This column also produced the most well-defined breakthrough curve, yielding an exchange capacity of 8.76 mg/g, equivalent to 0.437 meq/g for Ca2+ and 0.720 meq/g for Mg2+. These findings indicate that the 30 mm diameter provides an optimal balance between contact time and flow distribution, resulting in superior ion exchange efficiency.