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All Journal Rekayasa Mesin
Sinurat, David Fernando
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Mechanical Engineering

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THERMODYNAMIC ANALYSIS OF ALKALINE ELECTROLYSIS UNDER VISIBLE LIGHT ILLUMINATION: COMPARATIVE ASSESSMENT OF GREEN AND BLUE LED EXPOSURE Santoso, Mardi; Ahmad, Anton Royanto; Sinurat, David Fernando; Hamidi, Nurkholis; Purnami
Jurnal Rekayasa Mesin Vol. 16 No. 3 (2025)
Publisher : Jurusan Teknik Mesin, Fakultas Teknik, Universitas Brawijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21776/

Abstract

This study explores the thermodynamic behavior of alkaline electrolysis under visible light illumination, focusing on the effects of green and blue wavelengths in the absence of chemical additives. Through a series of controlled experiments, temperature evolution, energy input, and thermal efficiency were analyzed over a 20-minute electrolysis period. Results show that both green and blue light enhance the system's thermal response compared to dark (control) conditions, with blue light achieving the highest temperature rise and energy conversion efficiency. Arrhenius analysis revealed a clear temperature dependence of the rate constant, and strong correlations were observed between temperature rise (ΔT), heat energy (Q), and system efficiency. These findings suggest that visible light particularly blue light can significantly improve the thermal dynamics of electrolysis systems, paving the way for low-cost, passive solar-assisted hydrogen production.
Co-Authors Anton Royanto Ahmad Mardi Santoso Nurkholis Hamidi Purnami