The volatility of cryptocurrency markets has increased substantially in recent years, particularly for Ethereum (ETH), which exhibits fat-tailed distributions and persistent volatility clustering that traditional linear models are unable to capture. This study aims to analyze and model the volatility of ETH/USD using high-frequency hourly data to determine the most appropriate volatility model for describing Ethereum’s intraday market dynamics. The dataset consists of 8,760 hourly closing prices from October 31, 2024 to October 31, 2025, obtained through the CryptoCompare API. The methodological framework includes data preprocessing, log-return transformation, stationarity analysis using the Augmented Dickey–Fuller test, detection of heteroskedasticity via the ARCH–LM test, and estimation of several ARCH and GARCH model specifications. The results show that ETH/USD returns are stationary, non-normally distributed, and exhibit clear volatility clustering. Among the ARCH models, only ARCH(1) adequately captures short-term fluctuations, while ARCH(2) provides no additional benefit. In contrast, GARCH models demonstrate superior performance in capturing both short-term shocks and long-term persistence. Based on AIC, BIC, and log-likelihood values, GARCH(1,2) emerges as the best-performing model, offering the highest flexibility in representing Ethereum’s persistent and reactive volatility patterns. These findings confirm that ETH/USD volatility is predictable and can be modeled statistically. Future research may incorporate asymmetric GARCH extensions or external explanatory variables to improve predictive performance.