Indonesian Journal of Chemistry
Vol 19, No 4 (2019)

Extraction of Hydroxyapatite from Fish Scales and Its Integration with Rice Husk for Ammonia Removal in Aquaculture Wastewater

Sofiah Hamzah (School of Ocean Engineering, Universiti Malaysia Terengganu, 21030 Kuala Nerus, Terengganu, Malaysia)
Norhafiza Ilyana Yatim (School Marine Science and Environment, Universiti Malaysia Terengganu, 21030 Kuala Nerus, Terengganu, Malaysia)
Maslinda Alias (School of Ocean Engineering, Universiti Malaysia Terengganu, 21030 Kuala Nerus, Terengganu, Malaysia)
Asmadi Ali (School Marine Science and Environment, Universiti Malaysia Terengganu, 21030 Kuala Nerus, Terengganu, Malaysia)
Nazaitulshila Rasit (School of Ocean Engineering, Universiti Malaysia Terengganu, 21030 Kuala Nerus, Terengganu, Malaysia)
Azzam Abuhabib (School of Ocean Engineering, Universiti Malaysia Terengganu, 21030 Kuala Nerus, Terengganu, Malaysia)



Article Info

Publish Date
13 Aug 2019

Abstract

Aquaculture plays an important role in providing food and generate high income in many developing countries but the abundance of ammonia discharged from aquaculture wastewater gives the problem to the environment. This study focused on the extraction of hydroxyapatite (HAp) from fish scales and its modification with rice husk to produce bio-adsorbent for ammonia removal from aquaculture wastewater. The comparison has been made for the HAp preparation via microwave irradiation, alkaline heat treatment, and thermal decomposition method. X-ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FTIR) were used to analyze the surface chemistry and crystallinity of HAp, respectively. While the morphology of the HAp was observed under a Scanning Electron Microscope (SEM). Hydroxyapatite extracted via thermal decomposition method shows the best performance about 79% of ammonia removal at 210 min contact time which selected for coating agent of rice husk (RH/HAp) and was successfully removed 84% at 60 min saturation time. The result shows thermal decomposition is the best technique to extract HAp from fish scales and its integration with rice husk exhibited a better performance of bio-adsorbent. The findings of this study provide useful fundamental knowledge and platform for the development and improvement of aquaculture wastewater treatment system in the future.

Copyrights © 2019






Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...