ASEAN Journal of Chemical Engineering
Vol 14, No 2 (2014)

Lignin Removal From Aqueous Solution Using Calcium Lactate: The Effect Of Polymers And Magnesium Hydroxide As A Flocculant Aids

A. Y. Zahrim (Chemical Engineering Programme, Faculty of Engineering, Universiti Malaysia Sabah, Jalan UMS, 88400 Kota Kinabalu, Sabah, Malaysia
Sustainable Palm Oil Research Unit, Universiti Malaysia Sabah, Jalan UMS, 88400 Kota Kinabalu, Sabah, Malaysia)

A. Nasimah (Chemical Engineering Programme, Faculty of Engineering, Universiti Malaysia Sabah, Jalan UMS, 88400 Kota Kinabalu, Sabah, Malaysia
Sustainable Palm Oil Research Unit, Universiti Malaysia Sabah, Jalan UMS, 88400 Kota Kinabalu, Sabah, Malaysia)

S. Rosalam (Chemical Engineering Programme, Faculty of Engineering, Universiti Malaysia Sabah, Jalan UMS, 88400 Kota Kinabalu, Sabah, Malaysia)



Article Info

Publish Date
19 Mar 2015

Abstract

Palm oil mill effluent (POME) which is mainly associated with lignin has becoming a major concern due to its highly coloured appearance. The main colourant, i.e. lignin particles are difficult to be degraded in oil palm conventional biological ponding system. Coagulation/flocculation could remove the lignin prior to biological treatment and is considered vital to minimize the recalcitrance nature of palm oil mill effluent particles. In this study, the coagulation/flocculation process was investigated to remove lignin particles from aqueous solution. A non-toxic and biodegradable chemical i.e. calcium lactate was utilized as a destabilizer for the removal of lignin with an addition of several flocculants aid i.e. anionic polyacrylamide (APAM), polydimethyldiallylammonium chloride (polyDADMAC) and magnesium hydroxide. The effect of coagulant and flocculant aids dosage was investigated. From this study, it was found that the optimum condition was at 0.7g/L of calcium lactate and 0.5-1.0mg/L of APAM with ~64% of lignin removal. At concentration of 4 mg/L, the removal of lignin for APAM and polyDADMAC is similar. This result shows that the calcium lactate has potential as a coagulant and the efficiency can be enhanced with an addition of polymeric flocculant aids.

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Journal Info

Abbrev

AJChE

Publisher

Subject

Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

The ASEAN Journal of Chemical Engineering publishes papers on Chemical Engineering, specifically but not limited to the areas of thermodynamics, reaction kinetics, transport phenomena, process control, environment, energy, biotechnology, corrosion, separation science, powder technology, materials ...