Jurnal Kimia (Journal of Chemistry)
Vol. 4, No. 2 Juli 2010

LAJU KOROSI DAN MEKANISME INHIBISI ALUMINIUM MURNI MENGGUNAKAN KALIUM DAN KALSIUM STEARAT

Tiurlina Siregar (Unknown)



Article Info

Publish Date
14 Nov 2012

Abstract

A research on corrosion rate and inhibition mechanism of pure aluminum using potassium stearate andcalcium stearate has been carried out. The objectives of this research were to explore the type of inhibitor ofpotassium stearate and calcium stearate, to understand the reaction mechanism of corrosion inhibition of aluminum,and to study the effect of the salts toward corrosion rate of aluminum in acidic condition.Potassium and calcium citrates were found to inhibit the corrosion of pure aluminum at concentration of 60ppm, in acidic (pH 3) condition, at 25oC. The inhibition efficiencies and relative corrosion rates were : 76 %; 0,31(calcium stearate) and 73 %; 0,31 (potassium stearate). The result of the study on surface adsorption, bychromatography and spectroscopy suggested that the aluminum inhibition mechanism by the potassium stearate andcalcium stearate anions was due to the formation of surface film as a consequence of the formation of complexbetween aluminum surface atoms / ions with stearate (monodentate ligans) which donate their lone pair electronstoward aluminum.

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Journal Info

Abbrev

jchem

Publisher

Subject

Chemistry

Description

Jurnal Kimia (Journal of Chemistry) publishes papers on all aspects of fundamental and applied chemistry. The journal is naturally broad in scope, welcomes submissions from across a range of disciplines, and reports both theoretical and experimental ...