YOUNGSTER PHYSICS JOURNAL
Vol 4, No 3 (2015): Youngster Physics Journal Juli 2015

STUDI PENGAPLIKASIAN EFEK FOTOKATALIS DARI LAPISAN ZnO:Ag TERHADAP DEGRADASI BAKTERI E.coli

Ndaru Adyono (Jurusan Fisika, Fakultas Sains dan Matematika, Universitas Diponegoro, Semarang)
Heri Sutanto (Jurusan Fisika, Fakultas Sains dan Matematika, Universitas Diponegoro, Semarang)
Iis Nurhasanah (Jurusan Fisika, Fakultas Sains dan Matematika, Universitas Diponegoro, Semarang)



Article Info

Publish Date
01 Jul 2015

Abstract

Research in the field of green technology using photocatalyst materials can be a solution to environmental pollution, especially contamination of aquatic bacteria. These materials absorb energy from the sun and form hydroxyl radicals that kill bacteria. Zinc oxide has a high photocatalytic efficiency with Eg 3.3 eV in the range of UV - visible light. ZnO can be modified by addition of silver in order to improve the effectiveness as well as anti-bacterial properties. ZnO:Ag 4% layers prepared with thermal spray coating method with deposition temperature at 250ºC and aneling temperature at 450 ºC. XRD measurements performed with CuKα radiation with wavelength at 1.54060 Å and the diffraction angle in range 20 ° - 70 °. The diffraction patterns were identified using the Crystallography Open Database (COD) and software QUALX. ZnO (Id 101-1259) phase and metal Ag (Id 151-2487) phase has formed, but there are also silver oxide phase AgO (Id 150-9488) and Ag2O (Id 150-9684). Crystallite size has been calculated using Debye-Scherrer equation resulted an average value 43.46 nm. The optical properties were measured using a UV-Vis spectrometer in the wavelength range 250-800 nm. Transmittance spectrum were converted into an absorbance spectrum using the Beer-Lambert law. Eg value were analyzed with methods tauc's plot. Linear extrapolation (αhν)2 against hν provide direct transition Eg value 3.1 eV. Photodegradation ability of ZnO:Ag layer performed on E.coli bacteria. TPC measurement results were analyzed using the degradation rate graph, Ct (bacteria concentration) against time exposure. The degradation rate values obtained 1.554 x 10-17 (cfu/ml)-2(minutes)-1.Keywords : ZnO:Ag, band gap energy, XRD, Uv-Vis, TPC, degradation rate.

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