YOUNGSTER PHYSICS JOURNAL
Vol 3, No 3 (2014): Youngster Physics Journal Juli 2014

ANALISIS SIFAT OPTIK LAPISAN TIPIS BILAYER ZnO/TiO2 YANG DIDEPOSISIKAN MENGGUNAKAN METODE SOL-GEL SPRAY COATING DAN APLIKASINYA SEBAGAI FOTODEGRADASI ZAT WARNA

Hanum Yuda Aditya (Jurusan Fisika, Fakultas Sains dan Matematika, Universitas Diponegoro, Semarang)
Heri Sutanto (Jurusan Fisika, Fakultas Sains dan Matematika, Universitas Diponegoro, Semarang)



Article Info

Publish Date
01 Jul 2014

Abstract

ZnO/TiO2 bilayer thin films have been deposited on a glass substrate by using sol-gel method with spin coating technique. The quality of films deposited on buffer layer is found to be superior to those grown directly on a substrate. The ability of photodegradation of ZnO/TiO2 was observed through the dye test by various molarities of ZnO solution. ZnO sol was prepared by dissolving zinc acetate dehydrate into a solvent of isopropanol then add monoethanolamine and stirred for 30 min at 70°C. For preparing TiO2 sol, titanium tetraisopropoxide is first dissolved in a mixture containing isopropanol and ethanol at room temperature. Then after 30 min stirring, the sol was titrated with a mixture of acetic acid, ethanol and deionized water. The process was followed by 60 min at room temperature. ZnO sol as a first layer is first deposited on a glass substrate and then proceed TiO2 sol on it, for the both deposition was heated at 450oC. The optical properties of ZnO/TiO2 bilayer thin films was characterized by using spectrophotometer UV-Vis. The results showed that the molarity of the ZnO sol affects the optical properties of ZnO/TiO2 bilayer thin films. The band gap energy of the ZnO/TiO2 bilayer thin films with different molarity of ZnO sol respectively 0,1 M, 0,3 M, 0,5 M and 0,7 M has been measured about 3,21 eV, 3,27 eV, 3,32 eV and 3,36 eV. The results of the photodegradation test of the ZnO/TiO2 bilayer thin films have been able degrade methylene blue up to 99,85%, methyl orange 50,68% and batik’s dye 49,87%.Keywords: sol-gel, spray coating, photocatalist, ZnO/TiO2, band gap energy

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