Indonesian Journal of Chemistry
Vol 3, No 3 (2003)

THE USE OF GRIGNARD REAGENT IN PHEROMONE SYNTHESIS FOR PALM WEEVIL (Rhynchorus, Sp)

Warsito Warsito (Jurusan Kimia Fakultas MIPA Universitas Brawijaya)
Edi Priyo Utomo (Jurusan Kimia Fakultas MIPA Universitas Brawijaya)
Achmad Ashadi (Jurusan Kimia Fakultas MIPA Universitas Brawijaya)
Satriyo Santosa (Balai Proteksi Tanaman Perkebunan ( BPTP)-Jombang)



Article Info

Publish Date
09 Jun 2010

Abstract

In an integrated controlling system of palm weevil, using of synthetic feromoid is strickly needed. The research is aimed to synthesize pheromone which secreted by the weevil, e.g. 4-methyl-5-nonanol (R. ferrugineus) and 3-methyl-4-octanol (R. schach) through Grignard reagent which formed in situ.The synthesis was proceded by retrosynthesis to determine the precursor, valeraldehyde. The precursor was reacted with Grignard reagent of sec-amyl magnesium bromide (R. ferrugenieus) and sec-butyl magnesium bromide (R. shach) which made in situ. Characterization of the synthetic molecular pheromone was performed by Gas Chromatography-mass spectroscopy and Fourier Transformed Infra Red. The bioassay of the molecule was carried out by olfactometer.The result showed that the conversion of the reactions were 51.28% (4-methyl-5-nonanol) and 85.90% (3-methyl-4-octanol). The character of physico-chemical and bioactivity of the synthetic pheromone are identic with natural pheromones.

Copyrights © 2003






Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...