Indonesian Journal of Chemistry
Vol 20, No 6 (2020)

In-Situ Ionic Imprinted Membrane (IIM) Synthesis Based on Acetic Polyeugenoxy Acetyl Tiophen Methanolate for Gold(III) Metal Ion Transports

Muhammad Cholid Djunaidi (Department of Chemistry, Faculty of Science and Mathematics, Diponegoro University, Jl. Prof. Soedharto SH, Tembalang, Semarang 50275, Indonesia)
Pardoyo Pardoyo (Department of Chemistry, Faculty of Science and Mathematics, Diponegoro University, Jl. Prof. Soedharto SH, Tembalang, Semarang 50275, Indonesia)
Didik Setiyo Widodo (Department of Chemistry, Faculty of Science and Mathematics, Diponegoro University, Jl. Prof. Soedharto SH, Tembalang, Semarang 50275, Indonesia)
Retno Ariadi Lusiana (Department of Chemistry, Faculty of Science and Mathematics, Diponegoro University, Jl. Prof. Soedharto SH, Tembalang, Semarang 50275, Indonesia)
Anggun Yuliani (Department of Chemistry, Faculty of Science and Mathematics, Diponegoro University, Jl. Prof. Soedharto SH, Tembalang, Semarang 50275, Indonesia)



Article Info

Publish Date
06 Apr 2020

Abstract

In this research, Polyeugenoxy Acetyl Tiophen Methanolate (PEATM)-Au ionic imprinted membrane (IIM) was synthesized. IIM is a PEATM based membrane that has Au(III) ion molds. The PEATM synthesis was analyzed using FTIR spectroscopy, and its relative molecular weight was determined by the viscometry method. To find out the presence of Au(III) templates on IIM, FTIR spectroscopy and SEM-EDX were used. The results of FTIR spectroscopy & SEM-EDX analysis prove the existence of Au(III) metal ion templates at IIM. Through FTIR spectra, it could be seen that the absorption area of the -OH group was widening. In the IIM, the CS group wave number (702.9 cm–1) also shifted to a larger wavenumber (848.68 cm–1), this is likely due to the presence of PEGDE as a crosslinker agent and PVA as a plasticizer on the membrane that interacts with PEATM-Au, which influences the shift of vibrational wavenumber of CS bonds. It was also found that the most effective pH of the feed phase for the transport was at pH 3, and the most optimum transport time was 24 h for IIM and 48 h for NIM. The transport of Au in binary mixture of Au/Cd, Au/Fe, and Au/Pb also proves that the presence of Au(III) ions in IIM makes IIM more selective to Au(III) metal ions than NIM when used for the transport process as it transports Au more than the other metals. These results were as expected by using the HSAB theory as its groundwork.

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Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...