Chemistry Indonesian Journal of Chemical Research
Vol 8 No 3 (2021): Edition for January 2021

The Effectiveness of Magnetite Modified Gallic Acid Synthesized by Sonochemical Method As AuCl4- Adsorbent-Reductor

Rahmayanti, Maya (Unknown)
Santosa, Sri Juari (Unknown)
Sutarno, Sutarno (Unknown)
Paweni, Astuti (Unknown)



Article Info

Publish Date
31 Jan 2021

Abstract

In recent years gallic acid has been developed as an AuCl4- adsorbent-reducing agent. In this research, gallic acid was modified with magnetite by sonochemical method (GA-Fe3O4), and its effectiveness as an AuCl4- adsorbent was studied. GA-Fe3O4 was synthesized through one-stage (GA-Fe3O4-SK1) and two-stage (GA-Fe3O4-SK2) methods. The effectiveness of GA-Fe3O4 was studied through optimization studies on pH, time, kinetics, and isotherm adsorption of AuCl4-. The adsorption method used was the batch method in the pH range 2-7. While the kinetics model used was the Lagergren and Ho kinetics model. The adsorption isotherm model used was the Freundlich and Langmuir isotherm model. The results showed that the optimum pH conditions for adsorption of AuCl4- on GA-Fe3O4 occurred at pH 3. Adsorption of AuCl4- on GA-Fe3O4-SK1 and GA-Fe3O4-SK2 both followed the Ho kinetic model, while the adsorption isotherm followed the Freundlich isotherm model with values KF were 0.041 and 0.034 mol/g respectively.

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Journal Info

Abbrev

Indonesian Journal of Chemical Research (Indones.

Publisher

Subject

Biochemistry, Genetics & Molecular Biology Chemistry Engineering Environmental Science

Description

Indo. J. Chem. Res. is a journal that regularly publishes primary articles covering all branches of chemistry and its sub-disciplines. Published articles consist of complete research, short communication, and review articles. The scope of published articles is not limited to inorganic chemistry, ...