Reaktor
Volume 20 No.3 September 2020

Kinetic Study of Kapok Seed Oil Esterification using BMIM-PF6 Catalyst

Bagus Agang Sudrajat (Chemical Engineering Department, Faculty of Engineering Diponegoro University)
Widayat Widayat (Center of Biomass and Renewable Energy (C-BIORE), UPT Laboratorium Terpadu Universitas Diponegoro)
Ngurah Widiantara (Chemical Engineering Department, Faculty of Engineering Diponegoro University)
Hantoro Satriadi (Chemical Engineering Department, Faculty of Engineering Diponegoro University)
Maria Siahaan (Chemical Engineering Department, Faculty of Engineering Diponegoro University)
Wira Pinem (Chemical Engineering Department, Faculty of Engineering Diponegoro University)



Article Info

Publish Date
13 Oct 2020

Abstract

Biodiesel offers better combustion efficiency, lower sulfur content and aromatic compounds, higher cetane numbers than diesel fuel, biodegradable and renewable properties that are not possessed by conventional fuels such as diesel fuel. This study aims to study the modeling of esterification process of Kapok seed oil using 3 % liquid ionic catalyst 1-Butyl-3-MethydidazoliumHexafluorophosphate (BMIM-PF6). The validation results of reaction kinetic models for experiments and simulations provide an adjacent correlation value, that is R2 = 0.99526, with the rate constant value (k) based on experimental data are 0.003815 L/mol.s and 0.0038 L/mol.s for the simulation data. Based on the simulation results, the proper reaction order for this esterification reaction is the first order reaction equation with a value of R2 = 0.99526, while the second order reaction gives the value R2 = 0.89453. The reaction kinetics parameters obtained from the experimental results are A = 0.012 L/mol.s and -Ea = -0.437 kJ/mol, while the reaction parameters of the simulation are A = 1.0384 L/mol.s and -Ea = -89.5 kJ/mol.Keywords: Esterification, Ionic Liquid Catalyst, Kinetic

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Journal Info

Abbrev

reaktor

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Control & Systems Engineering Energy Materials Science & Nanotechnology

Description

Reaktor invites contributions of original and novel fundamental research. Reaktor publishes scientific study/ research papers, industrial problem solving related to Chemical Engineering field as well as review papers. The journal presents paper dealing with the topic related to Chemical Engineering ...