Indonesian Journal of Chemistry
Vol 20, No 6 (2020)

Comparative Study of Various Kinetic Models on Leaching of NCA Cathode Material

Soraya Ulfa Muzayanha (Department of Chemical Engineering, Faculty of Engineering, Universitas Sebelas Maret, Jl. Ir. Sutami 36 A, Surakarta 57126, Central Java, Indonesia
Pertamina Research & Technology Center, PT. PERTAMINA, Jl. Raya Bekasi Km. 20, Pulogadung, Jakarta 1)

Cornelius Satria Yudha (Department of Chemical Engineering, Faculty of Engineering, Universitas Sebelas Maret, Jl. Ir. Sutami 36 A, Surakarta 57126, Central Java, Indonesia)
Luthfi Mufidatul Hasanah (Department of Chemical Engineering, Faculty of Engineering, Universitas Sebelas Maret, Jl. Ir. Sutami 36 A, Surakarta 57126, Central Java, Indonesia)
Linggar Tungga Gupita (Department of Chemical Engineering, Faculty of Engineering, Universitas Sebelas Maret, Jl. Ir. Sutami 36 A, Surakarta 57126, Central Java, Indonesia)
Hendri Widiyandari (Department of Physics, Faculty of Mathematic and Natural Science, Universitas Sebelas Maret, Jl. Ir. Sutami 36 A, Surakarta 57126, Central Java, Indonesia)
Agus Purwanto (Department of Chemical Engineering, Faculty of Engineering, Universitas Sebelas Maret, Jl. Ir. Sutami 36 A, Surakarta 57126, Central Java, Indonesia)



Article Info

Publish Date
05 Jun 2020

Abstract

The kinetics study of NCA leaching in the HCl system was proposed. Various kinetic models such as shrinking core, logarithmic rate law, and Avrami equation were used to find out the most appropriate kinetic models for this process. The effect of HCl concentrations, leaching temperatures, solid to liquid (S/L) ratio, and leaching duration were observed. The optimum conditions of NCA leaching were at HCl concentration of 4 M, temperature of 80 °C, S/L ratio of 100 g/L, and leaching time of 1 h. The result shows that shrinking core model with diffusion control process of residue layer describes well the leaching mechanism in this research, which is indicated by the good fitting of coefficient values of correlation (R2) and confirmed by the activation energy values of Ni, Co, Al that were less than 40 kJ/mol.

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Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...