ASEAN Journal of Chemical Engineering
Vol 21, No 1 (2021)

The Effect of Amino-functionalization on Photoluminescence Properties of Sugarcane Bagasse-derived Carbon Quantum Dots

Muhammad Wahyu Nugraha (Department of Chemical Engineering, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, Perak 32610, Malaysia)
Nonni Soraya Sambudi (Centre of Urban Resource Sustainability (CUReS), Universiti Teknologi PETRONAS, Seri Iskandar, Perak, 32610, Malaysia)
Laksmi Dewi Kasmiarno (Department of Chemical Engineering, Universitas Pertamina, Simprug, Jakarta Selatan, 12220, Indonesia)
Norashikin Ahmad Kamal (Department of Civil Engineering, Universiti Teknologi MARA (UiTM) Shah Alam, Selangor, 40450, Malaysia)



Article Info

Publish Date
30 Jun 2021

Abstract

In the present study, amino-functionalized carbon quantum dots (N-CQDs) were prepared from sugarcane bagasse using a simple one-pot hydrothermal method. Both ethylenedinitrilotetraacetic (EDTA) & ethylenediamine (EDA) were used as carbon and amino sources, respectively. The emerging utilization of natural carbon precursors is critically essential considering its low cost, eco-friendly, and unexploited by-products (e.g., sugarcane bagasse), which may have sustainable economic and strategic benefits. The as-prepared N-CQDs were characterized using High-Resolution Transmission Electron Microscope (HRTEM), Fourier Transform Infrared Spectroscopy (FTIR), UV-vis absorption spectroscopy, and photoluminescence spectroscopy. The influences of amine groups were investigated. The as-prepared N-CQDs photoluminescence intensity increased and quenched significantly with EDTA and EDA amino-functionalization, respectively, with the highest quantum yield at 21.21%, 2.4 times higher than non-functionalized CQDs. Furthermore, the amino-functional groups can alter the CQDs structure and particle size ranging from 4.197±1.058 nm to 9.704±1.428 nm. Hence, the N-CQDs produced exhibit highly tunable photoluminescence and particle size potentially applicable in diverse applications.

Copyrights © 2021






Journal Info

Abbrev

AJChE

Publisher

Subject

Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

The ASEAN Journal of Chemical Engineering publishes papers on Chemical Engineering, specifically but not limited to the areas of thermodynamics, reaction kinetics, transport phenomena, process control, environment, energy, biotechnology, corrosion, separation science, powder technology, materials ...