Jurnal Ilmu dan Teknologi Kelautan Tropis
Vol. 12 No. 2 (2020): Jurnal Ilmu dan Teknologi Kelautan Tropis

STUDI KINETIKA ADSORPSI DAN DESORPSI ION FOSFAT (PO42-) DI SEDIMEN PERAIRAN SEMARANG DAN JEPARA

Lilik Maslukah (Program Doktor Ilmu Kelautan, FPIK, Universitas Diponegoro, Semarang)
Muhammad Zainuri (Departemen Oseanografi, FPIK, Universitas Diponegoro, Semarang)
Anindya Wirasatriya (Departemen Oseanografi, FPIK, Universitas Diponegoro, Semarang)
Rikha Widiaratih (Pusat Kajian Mitigasi Bencana dan Rehabilitasi Pesisir, Universitas Diponegoro, Semarang)



Article Info

Publish Date
31 Aug 2020

Abstract

Adsorption and desorption are important processes that affect the distribution of chemicals in the environment. This research aims to determine the change pattern of PO42- concentration by time through adsorption and desorption simulations. The simulation process was conducted on sediments from Semarang and Jepara waters. Through the analysis of desorption process, the contribution of sediment input to the P ion can be determined, based on the release of ions PO42- at the beginning of time until the maximum conditions of the desorption process. The first and second order of (what) equations were used to determine the adsorption kinetics, while the isotherms of the adsorptions were determined based on the Langmuir and Freundlich models. The results show that the significant desorption process occurs during the first hour and the contribution of PO42- ions by Semarang sediments are three times higher than Jepara sediments. Based on the adsorption kinetics and isotherms, the second order of the equation model and the Langmuir model are more appropriate for both locations. This model assumes that the adsorption capacity is proportional to the number of active sites occupied by PO42- ions and the adsorption occurs in one homogeneous sedimentary layer. Semarang sediments have adsorp pollutants (P ions) ability greater than Jepara Sediments with capacity values respectively are 11.57 and 11.2 µmol g-1.

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Journal Info

Abbrev

jurnalikt

Publisher

Subject

Biochemistry, Genetics & Molecular Biology Decision Sciences, Operations Research & Management Library & Information Science

Description

Aims and Scope Journal of Tropical Marine Science and Technology (Jurnal Ilmu dan Teknologi Kelautan Tropis) is a scientific journal in the field of tropical marine science and technology. We have a aims and scope to focus in publishing a good quality scientific articles for dissemination of ...