CHEMICA Jurnal Teknik Kimia
Vol 7, No 2 (2020): Desember 2020

Reaction Kinetics of Ammonium Removal from Cow Urine by Struvite Formation Using a Baffle Column Reactor

Rizqi Rendri Anggriawan (Universitas Pembangunan Nasional "Veteran" Jawa Timur)
Fauziah Hilda Alvira (Universitas Pembangunan Nasional "Veteran" Jawa Timur)
Luluk Edahwati (Universitas Pembangunan Nasional "Veteran" Jawa Timur)



Article Info

Publish Date
19 Jan 2021

Abstract

Reaction kinetics is the study of reaction rates and reaction mechanisms, which refers to determining the order and reaction rate constants of a given material. This study will examine the kinetics of the reaction of ammonium removal from cow urine by struvite formation. Cow urine contains NH4 which is high enough so that it can be used as material for the manufacture of struvite. Struvite (MgNH4PO4.6H2O) is a white crystalline material consisting of magnesium, ammonium, and phosphate in equimolar. The experiment was conducted with a temperature setting of 25, 35, 45, and 65 ËšC. The flow rates used were 8.8, 11, 14.67, 22, and 44 mL/min. The process of making struvite was carried out by crystallization at pH 9, molar ratio of 3:1:1, also air rate of 0.4 L/min. The study carried out following the first order with the best conversion was 0.7797 at 8.8 ml/min and 65 ËšC. The activation energy is 3123.82 J/mol and the collision frequency is 0.0379. The equation of reaction rate k = 0.0379 e-375,73/T (K-1).

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Journal Info

Abbrev

CHEMICA

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Energy

Description

CHEMICA Jurnal Teknik Kimia ISSN, 2355-875X (print) 2355-8776 (online) is a journal that publishes manuscripts or scientific papers in Chemical Engineering. The scope of this journal covers chemical reaction techniques, separation, optimization, process control, process system engineering, waste ...