Journal of Physics: Theories and Applications
Vol 4, No 1 (2020): Journal of Physics: Theories and Applications

Study of co-precipitated nanomaterials magnetic MnxCo1-xFe2O4 (with x = 0.50 & 0.75) for Photocatalyst Application in MB degradation

Wahid Sidik Sarifuddin (Sebelas Maret University)
Utari Utari (Sebelas Maret University)
Budi Purnama (Sebelas Maret University)



Article Info

Publish Date
29 Mar 2020

Abstract

The crystalline structure and magnetic properties of Mn1-xCoxFe2O4 (x = 0 & 0.25) was studied in this report. The ferrite materials were synthesized by the chemical co-precipitation method and calcinated at 1000oC for 5 hours. The obtained materials were characterized by FTIR, XRD and VSM, and for photocatalytic activity was measured by UV-Vis spectrometer. Vibration bands at tetrahedral and octahedral site were corresponded by  = 581.56 cm-1 and  = 465.83 cm-1 and 474.51 cm-1 . The obtained ferrite were confirmed by XRD as spinel structure and shown that the addition of number of Mn decreased crystallite size (D) and x-ray density (ρx), but lattice constants (a) increased. The crystallite size of samples with x = 0.50 was 34.85 nm, and x = 0.75 was 32.17 nm. The magnetic properties of nanoparticles shown that magnetization saturation (Ms)from 42.05 emu/g to 54.16 emu/g increased with the addition of number of Mn. The coercive field (Hc)decreased from 408.27 Oe to 258.37 Oe. Photocatalytic activity was observed by UV-Vis spectrometer, where percentage of MB degradation (E) increase with the addition of number on Mn from 49.08% to 69.06%, either rate constant (kapp) and half life time (t1/2).  Furthermore, ferrite material base Mn-Co-ferrite has good characteristic to applied for photocatalyst.

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Journal Info

Abbrev

jphystheor-appl

Publisher

Subject

Education Materials Science & Nanotechnology Physics

Description

Journal of Physics: Theories and Applications (cited as J. Phys.: Theor. Appl.) is a peer-reviewed and open access journal, which is published twice a year by Physics Department, Sebelas Maret University. The journal is designed to serve researchers, developers, professionals, graduate students and ...