Indonesian Journal of Chemistry
Vol 21, No 4 (2021)

Performance of N,O-Carboxymethyl Chitosan as Corrosion and Scale Inhibitors in CO2 Saturated Brine Solution

Muhamad Jalil Baari (Department of Chemistry, Universitas Sembilanbelas November Kolaka, Jl. Pemuda, Kolaka, 93511, Indonesia)
Bunbun Bundjali (Department of Chemistry, Institut Teknologi Bandung, Jl. Ganesha No. 10, Bandung 40132, Indonesia)
Deana Wahyuningrum (Department of Chemistry, Institut Teknologi Bandung, Jl. Ganesha No.10, Bandung 40132, Indonesia)



Article Info

Publish Date
21 May 2021

Abstract

The presence of salts and dissolved gas like CO2 that is carried with natural gas and crude oil along the pipeline is the main reason for corrosion and scale formation. These problems are usually resolved separately by corrosion inhibitors and scale inhibitors or acidification. Meanwhile, utilizing a compound to resolve both corrosion and scale formation has an advantage in the economic side and working time. N,O-carboxymethyl chitosan or N,O-CMCs is one of the chitosan's derivates. It is water-soluble and has different functional groups. Those properties support its capability as a complexing agent on corrosion and scale inhibitors. Synthesis of N,O-CMCs was carried out by chemical reactions between chitosan and chloroacetic acid under alkaline circumstances. N,O-CMCs product was characterized using FT-IR and 1H-NMR spectroscopy. The inhibition efficiency was analyzed by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization techniques. The measurements showed that the highest efficiency of corrosion inhibition reached 63.54% when the concentration and temperature were 30 ppm and 35 °C, respectively. N,O-CMCs was classified as a mixed-type inhibitor. The adsorption mechanism of the inhibitor followed Langmuir adsorption isotherm. The static scale inhibition test informed that the optimum inhibition efficiency of N,O-CMCs reached 60.00%.

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Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...