VALENSI
Jurnal Kimia VALENSI Volume 7, No. 2, November 2021

Photocatalytic Degradation of Methylene Blue and Methyl Orange by Y-PTC Metal-Organic Framework

Adawiah Adawiah (Integrated Laboratory Centre, Faculty of Science and Technology, UIN Syarif Hidayatullah Jakarta Jl. Ir. H. Juanda No. 95 Ciputat South Tangerang 15412, Indonesia)
Muhammad Derry Luthfi Yudhi (Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Indonesia Jl. Lingkar Kampus Raya, Pondok Cina, Beji, Depok, Jawa Barat 16424, Indonesia)
Agustino Zulys (Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Indonesia Jl. Lingkar Kampus Raya, Pondok Cina, Beji, Depok, Jawa Barat 16424, Indonesia)



Article Info

Publish Date
23 Nov 2021

Abstract

The yttrium based metal-organic framework (MOF) Y-PTC was synthesized by the solvothermal method using perylene as the linker and yttrium as metal ion. This study aims to assess the photocatalytic activity of yttrium-perylenetetracarboxylate (Y-PTC) metal-organic framework (MOF) toward methylene blue and methyl orange under visible light irradiation. The results of the FTIR analysis showed that Y-PTC MOF had a different structure and composition from its precursor (Na4PTC). The Y-PTC MOF has a bandgap energy value of 2.20 eV with a surface area of 47.7487 m2/g. The SEM-EDS analysis showed an elemental composition of yttrium, carbon, and oxygen, were 6.9%, 72.1% and 20.7%, respectively. Furthermore, Y-PTC MOF was able to adsorb dyes at the optimum by 78.10% and 35.57% toward methylene blue (MB) and methyl orange (MO) at the dispersion period of 60 mins. Y-PTC MOF exhibited photocatalytic activity towards the degradation of methylene blue and methyl orange under visible light irradiation. The addition of H2O2 inhibited Y-PTC photocatalytic activity towards MO degradation from 50.89% to 26.38%. In contrast to MO, the addition of H2O2 had a positive effect on MB, which increased the degradation from 87.56% to 91.65%. Therefore, Y-PTC MOF possessed the potential of a photocatalyst material in dyes degradation under visible light irradiation.

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Journal Info

Abbrev

valensi

Publisher

Subject

Chemistry

Description

Jurnal Kimia Valensi is a biannual and peer-reviewed open access journal published by Department of Chemistry, Faculty of Science and Technology UIN Syarif Hidayatullah Jakarta. This journal covering all aspect of ...