Journal of Engineering and Technological Sciences
Vol. 45 No. 3 (2013)

Characterization of Chemical and Physical Properties of Hydroxypropylated and Cross-linked Arrowroot (Marantha arundinacea) Starch

Rijanti Rahaju Maulani (Study Program of Agricultural Engineering, School of Life Science and Technology, Bandung Institute of Technology)
Dedi Fardiaz (Department of Food Science and Technology, Faculty of Agricultural Technology, Bogor Agricultural University)
Feri Kusnandar (Department of Food Science and Technology, Faculty of Agricultural Technology, Bogor Agricultural University)
Titi Candra Sunarti (Department of Agroindustrial Technology, Faculty of Agricultural Technology, Bogor Agricultural University)



Article Info

Publish Date
01 Dec 2013

Abstract

The modern food industry and a variety of food products require tolerant starch as raw material for processing in a broad range of techniques, from preparation to storage and distribution. Dual modification of arrowroot starch using hydroxypropylation and cross-linking was carried out to overcome the lack of native arrowroot starch in food processing application. The modifications applied were: combined propylene oxide (8%, 10%, and 12%); sodium tri meta phosphate/STMP (1%, 2%, and 3%); and sodium tri poly phosphate/STPP (4%, 5%, and 6%). These modifications significantly affected the composition of the amylose and amylopectin and the amount of phosphorus in the granules. Higher amounts of phosphate salt gave a higher phosphorus content, which increased the degree of substitution (DS) and the degree of cross-link. Arrowroot starch that was modified using a concentration of 8-10% propylene oxide and 1-2% STMP : 3-5% STPP produced a starch with < 0.4% phosphorus content. A higher concentration of propylene oxide provided a higher degree of hydroxypropyl. The changed physical properties of the modified granular arrowroot starch were examined through SEM testing, and its changed crystalline patterns through X-ray diffraction measurements. Especially, provision of a high concentration of propylene oxide (12%) combined with 3% STMP : 6% STPP affected the granular morphology and the crystallinity.

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Journal Info

Abbrev

JETS

Publisher

Subject

Engineering

Description

Journal of Engineering and Technological Sciences welcomes full research articles in the area of Engineering Sciences from the following subject areas: Aerospace Engineering, Biotechnology, Chemical Engineering, Civil Engineering, Electrical Engineering, Engineering Physics, Environmental ...