Makara Journal of Science
Vol. 22, No. 4

Influences of Zn Concentration on Dielectric Properties of ZnxNi1-xFe2O4 Magnetic Nanoparticles

Suharyadi, Edi (Unknown)
Rahayu, Dwi Indah (Unknown)
Armitasari, Linda (Unknown)
Abraha, Kamsul (Unknown)



Article Info

Publish Date
20 Dec 2018

Abstract

Dielectric properties of ZnxNi1-xFe2O4magnetic nanoparticles (MNPs) with various Zn concentration (x = 0.2-0.8) havebeen investigated over a wide frequency range 5–120 kHz. Zn-Ni ferriteMNPs have spinel cubic structure. Thecrystallite size of the sample for x = 0.2 was about 21.5 nm and then decreases by increasing Zn concentration. For sample with x = 0.4 at frequency 20 kHz, the real dielectric constant (ε') was 35.9, imaginary dielectric constant (ε") was 20.4 and loss tangent (tanδ) was 0.6. Zn concentration would affect to availability of ferrous and ferric ions in the octahedral site which are preferentially occupied by Zn2+ion. The dielectric constants decrease with increasing frequency. The sample with at x = 0.6 has thehighest dielectric on frequency 5 kHz. The maximum AC conductivity(σAC) was 1.7 x 10-4 Ω-1 at 65 kHz observed for concentration x = 0.3. The dielectric constants and conductivity at low frequency are due to the existence of grains boundary while the dispersion in the high frequency region are due to the conducting grains.

Copyrights © 2018






Journal Info

Abbrev

publication:science

Publisher

Subject

Description

Makara Journal of Science publishes original research or theoretical papers, notes, and minireviews on new knowledge and research or research applications on current issues in basic sciences, namely: Material Sciences (including: physics, biology, and chemistry); Biochemistry, Genetics, and ...