Kaunia: Integration and Interconnection of Islam and Science Journal
Vol. 18 No. 2 (2022)

Adsorption and Desorption Metal Cu (II) using Zeolite Synthetic by Bottom Ash Coal Modified Dithizone

Yuan Sidarta (UIN Sunan Kalijaga Yogyakarta)
Didik Krisdiyanto (UIN Sunan Kalijaga Yogyakarta)
Khamidinal Khamidinal (UIN Sunan Kalijaga Yogyakarta)



Article Info

Publish Date
15 Dec 2022

Abstract

Zeolite synthetic and zeolite modified dithizone has been succesfully created by hydrotermal method. The aim of this research is to know the characteristics of zeolite synthetic and zeolite modified dithizone and to know capacity of adsorption and desorption. The effect of various variables, such as pH, concentration of Cu (II), contact time and temperature was investigated using batch process,  characterization zeolite modified dithizone and zeolite synthetic using XRD,  XRF, FTIR and GSA. The result of characterization bottom ash coal by hydrotermal reaction using XRF, be discovered composition Si as many 82,01% and Al 8,54%. product of melting hydrothermally indicate a specific zeolite IR absorption at a wavelength of 300-1250 cm-1. The result XRD showed that be found zeolite-X, zeolite-A, zeolite sodalite and difatogram of dithizone. Zeolite modified dithizone has been succesfully synthesized with a marked presence group of –NH and –SH by using FTIR. Zeolite modified dithizone surface area change from 160,262 m2/g to 69,609 m2/g. The best adsorption metal Cu(II) by zeolite synthetic is pH 7. Kinetics adsorption zeolite synthetic and zeolite modified dithizone follow kinetics of pseudo second orde, with R2 respectively 0,7378 and 0,8689, rate constant of pseudo second orde adsorption at zeolite synthetic  is -0,017 g/mg.min-1 and zeolite modified dithizone -0,013 g/mg.min-1. Isotherm type for both of adsorbent follow Langmuir isotherm. Desorption of metal Cu(II) on zeolite modified dithizone and zeolite synthetic a lot off obtained using HCl at level 47,08% and 41,49% respectively.

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Journal Info

Abbrev

kaunia

Publisher

Subject

Religion Biochemistry, Genetics & Molecular Biology Chemistry Mathematics Physics

Description

The aim of KAUNIA journal is to publish high-quality articles dedicated to all aspects of the latest outstanding developments in the field of Science, Mathematics, Education, Technology, and Religious Perspective Interconnect-Integration. The journal publishes articles, reviews, and research notes ...