Jurnal Teknik Kimia dan Lingkungan
Vol. 6 No. 2 (2022): October 2022

Delignification of Cassava Peel by Using Alkaline Hydrogen Peroxide Method: Study of Peroxide Concentration, Solid/Liquid Ratio, and pH

Dini Nur Afifah (1Department of Mechanical Engineering, Universitas Muhammadiyah Purwokerto, Jl. K.H Ahmad Dahlan 202, Purwokerto 53182, Indonesia)
Neni Damajanti (Department of Chemical Engineering, Universitas Muhammadiyah Purwokerto, Jl. K.H Ahmad Dahlan 202, Purwokerto 53182, Indonesia)
Maulani Mustholidah (Department of Chemical Engineering, Universitas Muhammadiyah Purwokerto, Jl. K.H Ahmad Dahlan 202, Purwokerto 53182, Indonesia)
Hariyanti (Departement of Pharmacy, Universitas Muhammadiyah Purwokerto, Jl. K.H Ahmad Dahlan 202, Purwokerto 53182, Indonesia)



Article Info

Publish Date
31 Oct 2022

Abstract

Cassava peel is a natural material with cellulose content reaching 33.33%. In order to utilize cassava peel as a biodegradable polymer and renewable energy alternative, a delignification process is essential to separate cellulose from hemicellulose and lignin, which prevents the penetration of cellulose hydrolyzer. The delignification method chosen in this study was alkaline hydrogen peroxide (AHP). The AHP is based on the autoxidation of lignin using hydrogen peroxide (H2O2) in an alkaline environment. This method was chosen because it can damage the lignocellulosic structure with relatively low energy and is more selective for lignin. However, under certain conditions, AHP can trigger carbohydrate depolymerization, which decreases yield. Therefore, it is necessary to study the effect of H2O2 concentration, Solid/Liquid ratio (S/L) (w/v), and pH to evaluate the effectiveness of lignin removal in cassava peel. The concentration of H2O2 was varied into 1.5%, 3%, 4.5%, 6%, and 7.5%. The S/L ratio is varied to 1:3, 1:5, 1:7, 1:9,1:12. The pH of the solution was varied to 8, 9, 10, 11, and 12. The reaction temperature was maintained at 70-90 °C for 3 hours. The results showed that lignin could be reduced to 84.05% for 3 hours by using 6% H2O2, an S/L ratio of 1:5, and a pH of 11. The reaction carried out under these conditions can also increase the amount of cellulose from 33.33% to 49.00%.

Copyrights © 2022






Journal Info

Abbrev

jtkl

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry Energy Engineering Materials Science & Nanotechnology

Description

JTKL editors welcome manuscripts in the form of research articles, literature review, or case reports that have not been accepted for publication or even published in other scientific journals. Articles published in cover key areas in the development of chemical and environmental engineering ...