Indonesian Journal of Chemistry
Vol 23, No 4 (2023)

Activated Charcoal from Coffee Dregs Waste as an Alternative Biosorbent of Cu(II) and Ag(I)

Susy Yunita Prabawati (Chemistry Program Study, Faculty of Science and Technology, UIN Sunan Kalijaga, Jl. Laksda Adisucipto, Yogyakarta 55281, Indonesia)
Priyagung Dhemi Widiakongko (Chemistry Program Study, Faculty of Science and Technology, UIN Sunan Kalijaga, Jl. Laksda Adisucipto, Yogyakarta 55281, Indonesia)
Mohammad Ahsani Taqwim (Chemistry Program Study, Faculty of Science and Technology, UIN Sunan Kalijaga, Jl. Laksda Adisucipto, Yogyakarta 55281, Indonesia)



Article Info

Publish Date
15 Aug 2023

Abstract

This study examines the use of coffee dregs waste as biosorbents of Cu(II) and Ag(I). Coffee dregs waste still contains a high level of carbon and cellulose for biosorbents production. The production process was started with charcoal activation using H3PO4. The batch method was applied by variations of contact time, the mass of the biosorbent, and the initial concentration of metal ions. The results showed that Cu(II) and Ag(I) were optimally adsorbed at pH 6 and 4, respectively. The amount of adsorbed metal ions increased with adsorption contact time. The adsorption process of both metal ions reaches stability within 60 min and the optimum biosorbent mass is 1 g. Isothermal adsorption studies show that Cu(II) adsorption tends to follow Langmuir isotherm with an adsorption energy of 31.42 kJ/mol and Ag(I) adsorption follows Freundlich isotherms with an adsorption energy of 27.74 kJ/mol. Based on the results, the interaction between metal ions and adsorbents is a chemical adsorption process and coffee dregs charcoal has the potential to adsorb Cu(II) and Ag(I) metal ions.

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Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...