JURNAL KIMIA SAINS DAN APLIKASI
Vol 26, No 6 (2023): Volume 26 Issue 6 Year 2023

Synthesis of Carbon Dot Nanoparticles (C-Dot) from Seeds and Seedpods of Kesumba Keling (Bixa orellana) using Hydrothermal and Solvothermal Methods

Amrina Rosyada (Department of Chemistry, IPB University, Gedung Kimia, Jalan Tanjung Kampus IPB, Dramaga, Babakan, Kec. Dramaga, Kabupaten Bogor, Jawa Barat 16680|IPB University|Indonesia)
Sri Sugiarti (Department of Chemistry, IPB University, Gedung Kimia, Jalan Tanjung Kampus IPB, Dramaga, Babakan, Kec. Dramaga, Kabupaten Bogor, Jawa Barat 16680|IPB University|Indonesia)
Irma Herawati Suparto (Department of Chemistry, IPB University, Gedung Kimia, Jalan Tanjung Kampus IPB, Dramaga, Babakan, Kec. Dramaga, Kabupaten Bogor, Jawa Barat 16680|IPB University|Indonesia)



Article Info

Publish Date
30 Sep 2023

Abstract

C-dot is a 0-dimensional nanoparticle with photoluminescence properties and can be synthesized from plants, such as the Kesumba Keling plant. Kesumba Keling contains a red pigment sourced from the bixin and norbixin dyes containing functional groups like ‒COOH and ‒COO‒. These functional groups are anticipated to enhance the luminescence intensity produced by C-dot. This research focuses on synthesizing C-dots from Kesumba Keling seeds and seedpods using hydrothermal and solvothermal methods. It also involves an analysis of how different solvents and passivation agents affect the luminescence of C-dots, along with a comparison of the resulting fluorescent colors. The highest yield, at 73.26%, was achieved when using Kesumba Keling seedpods and ethanol as the solvent without adding urea. Furthermore, C-dots synthesized using ethanol as the solvent display a stronger luminescent glow compared to those produced using double-distilled water as the solvent. Additionally, all C-dots synthesized in this study emit a blue luminescence. Characterizing C-dots using a UV-Vis spectrophotometer reveals absorption peaks at two different wavelengths: 260‒280 nm and 320‒340 nm. These absorption peak results align with C-dot characteristics, as confirmed by Fourier transform infrared spectrophotometry. When comparing the intensity of C-dots, those derived from Kesumba Keling peel using the double-distilled water solvent with the addition of urea exhibit a higher intensity (measuring at 0.99) than C-dots obtained from Kesumba Keling peel using ethanol as a solvent with added urea. The solvothermal method is deemed the most effective for C-dot synthesis, as it yields the highest luminescence intensity, accompanied by an emission wavelength shift to 491.65 nm.

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Journal Info

Abbrev

ksa

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry Engineering

Description

urnal Kimia Sains dan Aplikasi (p-ISSN: 1410-8917) and e-ISSN: 2597-9914) is published by Department of Chemistry, Diponegoro University. This journal is published four times per year and publishes research, review and short communication in field of ...