Indonesian Journal of Chemistry
Vol 23, No 5 (2023)

Facile Production of Biodiesel from Candlenut Oil (Aleurites moluccana L.) Using Photocatalytic Method by Nano Sized-ZnO Photocatalytic Agent Synthesized via Polyol Method

Hendro Juwono (Department of Chemistry, Faculty of Science and Data Analytics, Institut Teknologi Sepuluh Nopember, Kampus ITS Keputih, Sukolilo, Surabaya 60111, Indonesia)
Anisun Zakiyah (Department of Chemistry, Faculty of Science and Data Analytics, Institut Teknologi Sepuluh Nopember, Kampus ITS Keputih, Sukolilo, Surabaya 60111, Indonesia)
Riki Subagyo (Department of Chemistry, Faculty of Science and Data Analytics, Institut Teknologi Sepuluh Nopember, Kampus ITS Keputih, Sukolilo, Surabaya 60111, Indonesia)
Yuly Kusumawati (Department of Chemistry, Faculty of Science and Data Analytics, Institut Teknologi Sepuluh Nopember, Kampus ITS Keputih, Sukolilo, Surabaya 60111, Indonesia)



Article Info

Publish Date
16 Oct 2023

Abstract

Biodiesel production from non-edible oil is an alternative way to reduce edible oil dependency and reduce the competition for feed and food. Candlenut oil (Aleurites moluccana L.) is one of the non-edible oils which can be used as feedstock for biodiesel production since they have a high oil content. Herein, the biodiesel production from candlenut oil has been conducted using zinc oxide (ZnO) synthesized by the polyol method. Polyol methods facilitated the formation of ZnO nanoparticles with various shapes, including spherical, rod, and hexagonal. Besides, ZnO showed a mesoporous characteristic, facilitating the conversion of fat fatty acid to fatty acid methyl ester (FAME) of 61%. Increasing ZnO dosage led to enhancing the FAME yield. Similarly, the FAME yield was also improved by increasing the reaction time. The results of esterification of candlenut oil and methanol yielded 70.76% FAME with 2% nano-ZnO polyol catalyst at 180 min reaction time at room temperature whilst being stirred constantly at 400 rpm. A good FAME conversion using ZnO at room temperature provides good information to produce biodiesel with a simple method. Apart from that, photocatalytic promoted transesterification at room temperature, which is beneficial for reducing energy consumption.

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Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...