Indonesian Journal of Chemistry
Vol 24, No 1 (2024)

Characterization of Synthetic Humin from Solid Hydrolysate and Biochar from Hydrothermal Carbonization Products of Chicken Feather Waste

Siti Dewi Fatimah (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)
Agus Kuncaka (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)
Roto Roto (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)



Article Info

Publish Date
01 Feb 2024

Abstract

Solid hydrolysate and biochar 2:1 are synthetic humus from hydrothermal carbonization of chicken feather waste and contain humin that can be isolated by IHSS method. The recalcitrant humin is obtained in solid form. The yield of isolated humin from biochar 2:1 was 44.5%, and humin from solid hydrolysate was 12.7%. Analysis of humin by FTIR indicated the characteristics of complex functional groups. Based on the XRD and TEM tests, humin is formed from amorphous crystals with <14 nm in size and categorized as a superparamagnetic nanoparticle. The surface morphology of humin from solid hydrolysate is in the form of small spheres attached to larger particles, while humin from biochar 2:1 is smoother and has a larger surface area. This synthetic humin contains the nutrients N, O, Si, Cu, S, Mg, Zn, and K based on the EDX test quantitatively supported by AAS analysis. Characteristics of humin, which contains nutrients, are composed of amorphous crystals with complex functional groups during the hydrothermal carbonization process. Their relatively small heterogeneous molecules are stabilized by hydrophobic interactions and hydrogen bonds to form supramolecular compound associations in hour order. This humin content in synthetic humus is expected to increase its utility as a soil improver.

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Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...