Indonesian Journal of Chemistry
Vol 24, No 1 (2024)

Effect of Synthesis Temperature on Adsorbent Performance of Blending Anionic and Cationic Gels in Divalent Metal Ions Adsorption

Eva Oktavia Ningrum (Department of Industrial Chemical Engineering, Faculty of Vocational Studies, Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo, Surabaya 60111, Indonesia)
Suprapto Suprapto (Department of Industrial Chemical Engineering, Faculty of Vocational Studies, Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo, Surabaya 60111, Indonesia)
Saidah Altway (Department of Industrial Chemical Engineering, Faculty of Vocational Studies, Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo, Surabaya 60111, Indonesia)
Warlinda Eka Triastuti (Department of Industrial Chemical Engineering, Faculty of Vocational Studies, Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo, Surabaya 60111, Indonesia)
Afan Hamzah (Department of Industrial Chemical Engineering, Faculty of Vocational Studies, Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo, Surabaya 60111, Indonesia)
Agus Surono (Department of Industrial Chemical Engineering, Faculty of Vocational Studies, Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo, Surabaya 60111, Indonesia)
Lulu Sekar Taji (Department of Industrial Chemical Engineering, Faculty of Vocational Studies, Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo, Surabaya 60111, Indonesia)
Erlangga Ardiansyah (Department of Industrial Chemical Engineering, Faculty of Vocational Studies, Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo, Surabaya 60111, Indonesia)



Article Info

Publish Date
01 Feb 2024

Abstract

In this study, the anionic and cationic gels were synthesized separately using copolymerization between N-isopropylacrylamide (NIPAM) and acrylic acid or chitosan through a polymerization reaction using N,N'-methylenebisacrylamide (MBAA) as a cross-linker with various monomer concentrations and synthesis temperature. The anionic and cationic gels were blended to minimize inter-intra particle association and to improve the adsorption ability. The FTIR analysis found that the synthesis of the NIPAM-co-acrylic acid and NIPAM-co-chitosan gels was successfully carried out, indicating no presence of a vinyl group in the functional group. The result showed that the ion adsorption amount of Pb2+ ions blending gels increased significantly, almost twice compared to the adsorption before blending. The adsorption amount of Pb2+ ions increased with increasing the gel synthesis temperature. The adsorption amount follows the order of Pb2+ > Fe2+ > Ni2+. The adsorption amount of Pb2+ tends to decrease with increasing sedimentation volume. The higher the synthesis temperature, the larger the porous diameter formed. These results demonstrate that blending gel of NIPAM-co-chitosan and NIPAM-co-acrylic acid is a feasible alternative for removing heavy metal ions owing to its good adsorption performance.

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Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...