Indonesian Journal of Chemistry
Vol 24, No 1 (2024)

Cellulose Ethers from Banana (Musa balbisiana Colla) Blossom Cellulose: Synthesis and Multivariate Optimization

Safira Zidna Salama (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sebelas Maret, Jl. Ir. Sutami 36A, Surakarta 57126, Indonesia)
Maulidan Firdaus (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sebelas Maret, Jl. Ir. Sutami 36A, Surakarta 57126, Indonesia)
Venty Suryanti (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sebelas Maret, Jl. Ir. Sutami 36A, Surakarta 57126, Indonesia)



Article Info

Publish Date
01 Feb 2024

Abstract

Cellulose ethers are biocompatible polymers which have attracted considerable attention for various applications due to their physical and mechanical properties. The present work aims to find the optimum condition for synthesizing cellulose ethers from banana blossom cellulose (BBC) such as methylcellulose (MC), carboxymethyl cellulose (CMC) and hydroxypropyl cellulose (HPC). The ultrasonication-assisted method as an energy source is used to shorten the synthesis time at room temperature and obtain high yields. The influences of various parameters (NaOH concentration, etherification agents, and sonication time) were analyzed using a multivariate statistical modeling response surface methodology (RSM). The materials were characterized by FTIR, SEM, and TGA. The cellulose ethers obtained have the potential as food additives with DS values of 2.0, 0.7, and 0.86, respectively. MC was synthesized optimally with a yield of 96.52% using a composition of cellulose (0.4 g), 50% (w/v) NaOH (10 mL) and dichloromethane (6 mL). CMC was synthesized optimally with a yield of 98.26% using a composition of cellulose (0.4 g), 30% (w/v) NaOH (2 mL) and monochloroacetic acid (1 g). HPC was synthesized optimally with a yield of 97.51% using a composition of cellulose (0.4 g), 10% (w/v) NaOH (2 mL) and propylene oxide (1.5 mL).

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Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...