Jurnal Rekayasa Proses
Vol 2 No 2 (2008): Volume 2, Number 2, 2008

Pemodelan matematis reaksi oksidasi katalitik fero sulfat menjadi feri sulfat

Takdir Syarif (Jurusan Teknik Kimia, Fakultas Teknologi Industri Universitas Muslim Indonesia Jl. Urip Sumoharjo KM. 05, Makassar)
Andiyan Yuwono (Jurusan Teknik Kimia, Fakultas Teknik, Universitas Gadjah mada Jl Grafika No 2, Yogyakarta)



Article Info

Publish Date
31 Dec 2008

Abstract

Iron was dissolved in a sulfuric acid to form a concentrated ferrous sulphate (FeSO4) solution. This research was conducted to form ferric sulfate by catalytic oxidation of ferrous sulfate using manganese dioxide as catalyst. The system was a three-phase heterogeneous reaction with a quite complex kinetics The present study aimed at developing a mathematical modeling of three-phase reaction kinetics that involved gas, liquid and solid. Oxidation was undertaken in an isothermal isobaric condition in a three-neck flask reactor. The experiment was conducted in a temperature range of 323 to 353 K with a catalyst concentration of 1.7 g/L. The results indicated that the reaction kinetics could be approached with a quasi steady state model and the chemical reaction on the catalyst surface was the determining step.

Copyrights © 2008






Journal Info

Abbrev

jrekpros

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering

Description

Jurnal Rekayasa Proses is an open-access journal published by Chemical Engineering Department, Faculty of Engineering, Universitas Gadjah Mada as scientific journal to accommodate current topics related to chemical and biochemical process exploration and optimization which covers multi scale ...