Jurnal Rekayasa Proses
Vol 4 No 1 (2010): Volume 4, Number 1, 2010

Pemodelan dan simulasi kinetika reaksi alkoholisis minyak Jarak pagar (Jatropha curcas) dengan katalisator zirkonia tersulfatasi

Heri Rustamaji (Jurusan Teknik Kimia, Fakultas Teknik, Universitas Lampung)
Hary Sulistyo (Jurusan Teknik Kimia, Fakultas Teknik, Universitas Gadjah Mada)
Arief Budiman (Jurusan Teknik Kimia, Fakultas Teknik, Universitas Gadjah Mada)



Article Info

Publish Date
30 Jun 2010

Abstract

Jatropha oil is a very potential source of biodiesel fuel that can be processed through alcoholysis. In the present work, a study on alcoholysis of Jatropha oil with the use of solid acid catalyst was conducted in a wellmixed batch reactor. The study involved varying reaction temperatures of 100°C to 140°C, ethanol-oil molar ratio of 9, agitation speed of 1000 rpm and catalyst loading of 3% with respect to the oil. The reaction was carried out for 120 minutes; meanwhile samples were taken from the reactor every 15 minutes for glycerol analysis. In order to predict kinetics parameter of the alcoholysis reaction, a mathematical model of consecutive reactions was developed. The Matlab software was used to solve the simultaneous differential equations. Over the range of variables used in the experiment, the mathematical model was able to fit the experimental data quite well. The calculation results showed that the values of collision frequency factor for the consecutive reactions are 5.13 x 103; 5.682 x 103, and 2.534 x 103 (cm3/mgek) (cm3/g.cat/min). Meanwhile, the activation energies for the consecutive reaction are 4,176; 4,310 and 6,019 cal/mol.

Copyrights © 2010






Journal Info

Abbrev

jrekpros

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering

Description

Jurnal Rekayasa Proses is an open-access journal published by Chemical Engineering Department, Faculty of Engineering, Universitas Gadjah Mada as scientific journal to accommodate current topics related to chemical and biochemical process exploration and optimization which covers multi scale ...