Jurnal Rekayasa Proses
Vol 8 No 1 (2014): Volume 8, Number 1, 2014

Pemanfaatan abu sekam padi pada ozonisasi minyak goreng bekas untuk menghasilkan biodiesel

Lieke Riadi (Jurusan Teknik Kimia, Fakultas Teknik ,Universitas Surabaya Pusat Studi Lingkungan ,Universitas Surabaya Jalan Raya Kalirungkut, Surabaya, 60239)
Lanny Sapei (Jurusan Teknik Kimia, Fakultas Teknik ,Universitas Surabaya)
Yosephine Kristiani (Jurusan Teknik Kimia, Fakultas Teknik ,Universitas Surabaya)
Octovania Sugianto (Jurusan Teknik Kimia, Fakultas Teknik ,Universitas Surabaya)



Article Info

Publish Date
30 Jun 2014

Abstract

Biodiesel is one of the alternatives for the shortage of fossil fuel. In this experiment biodiesel from waste cooking oil which is made using an ozonation process was studied. The process is energy extensive and environmentally friendly because of the use waste cooking oil as a raw material and the experiment was carried out at low reaction temperature which is room temperature. Waste cooking oil was reacted with methanol, KOH as the base catalyst, and ozone that was continually flowed into a stirred reactor at 30oC and atmospheric pressure. The effect of rice hulk ash addition as the supporting catalyst on methyl esters concentrations was observed in this experiment. Two different types of ashes were used, namely black (heating at 350oC) and white (heating at 750oC) with the concentrations of 0.5; 1; 1.5% (w/w). Methyl esters products were characterized using GC apparatus for Short Chain Methyl Ester (SCME) and Long Chain Methyl Ester (LCME) concentrations. They were also analyzed in terms of density and viscosity. The ashes were characterized by XRD and BET. The highest amount of SCME was achieved at the white ash concentration of 1.5%. However, the ash additions seemed not significant on the LCME production. Thus, the white ash was more useful as a supporting catalyst than the black one.

Copyrights © 2014






Journal Info

Abbrev

jrekpros

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering

Description

Jurnal Rekayasa Proses is an open-access journal published by Chemical Engineering Department, Faculty of Engineering, Universitas Gadjah Mada as scientific journal to accommodate current topics related to chemical and biochemical process exploration and optimization which covers multi scale ...