ALCHEMY Jurnal Penelitian Kimia
Vol 20, No 1 (2024): March

Suppressed Ion Chromatographic Analysis of Anionic Macroelements in Nutmeg (Myristica fragrans) Diversity Specific to North Maluku

Muhammad Amin (Universitas Khairun)
Deasy Liestianty (Universitas Khairun)
Abu Rahmat Ibrahim (Universitas Khairun)
Nahdiah Amin (Gifu University)
Budhi Oktavia (Universitas Negeri Padang)



Article Info

Publish Date
30 Mar 2024

Abstract

This study proposed an ion chromatography method for analyzing anionic macroelements (fluoride, chloride, nitrite, bromide, nitrate, sulfate, and phosphate), and applied it to nutmeg (Myristica fragrans) diversity to explore the potential of nutmeg as an electrolyte. The analysis method was based on a suppressed conductivity system that simultaneously analyzed the anionic macroelements on Metrohm Supp A 250/4.0 column using 8.0 mM sodium carbonate (Na2CO3) and 0.25 mM sodium bicarbonate (NaHCO3) as a mixture eluent. Excellent peak resolution and completed separation were achieved within 18 min when the flow rate of the detector was 0.8 mL/min. The peak height with calibration curves at 2.5 ‒ 30.0 mg/L concentration ranges was obtained for all anionic macroelements. All collected nutmeg samples were specific to North Maluku. Based on the standard samples used, the analysis results revealed that only four anionic macroelements (chloride, nitrate, sulfate, and phosphate) were found in the nutmeg samples, and the concentration of each anion (e.g., chloride ion, and so) was different for each type of nutmeg. The highest total of anionic macroelements concentration was found in the Myristica succedanea (1605.05 mg/kg) nutmeg sample, while Myristica specioga had the lowest (661.76 mg/kg). The method was validated regarding the detection limit (LOD) and reproducibility.

Copyrights © 2024






Journal Info

Abbrev

alchemy

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry Energy Environmental Science Materials Science & Nanotechnology

Description

ALCHEMY Jurnal Penelitian Kimia is a chemistry journal published by Sebelas Maret University, Surakarta. ALCHEMY Jurnal Penelitian Kimia publishes original research articles or review articles in organic chemistry, inorganic chemistry, analytical chemistry, physical chemistry, biochemistry, and ...