JURNAL REKAYASA KIMIA & LINGKUNGAN
Vol 13, No 2 (2018): Jurnal Rekayasa Kimia & Lingkungan (December, 2018)

Perengkahan n-Butana Menggunakan Katalis Nanopartikel Zeolit Alam Klaten

Kurniawan, Teguh (Unknown)
Muraza, Oki (Unknown)



Article Info

Publish Date
25 Nov 2018

Abstract

Increasing demand on olefins, high energy consumption of thermal cracking and oil depletion are the driving force to find new process to produce olefins. Catalytic cracking of n-butane is promising route to produce olefins. In this paper, we synthesized nanoparticle from natural zeolites by ball milling-recrystallization method and studied the effect of acid dealumination over the nanozeolites on the catalytic properties. Particle size was evaluated visually by using scanning electron microscope. X-Ray Diffraction analysis was performed to study zeolites phase and its crystallinity. Acid dealumination effect over nanosized mordenite on the acidity were evaluated by ammonia TPD and pyridine FTIR. Textural properties of zeolites were characterized by nitrogen physisorption at -196 oC. The catalysts were tested in a fixed bed reactor for n-butane cracking to olefins product. Various temperature conditions were applied ranging from 350 oC to 650 oC for n-butane cracking in a fixed bed reactor. Conversions of n-butane were 15% and 90% at 350 oC and 650 oC, respectively. Selectivity to olefins was increase from 1% at 350 oC to 47% at 650 oC.

Copyrights © 2018






Journal Info

Abbrev

RKL

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Energy Engineering

Description

The Journal of Chemical Engineering and Environment is an open access journal that publishes papers on chemical engineering and environmental engineering. The following topics are included in these sciences: Food and biochemical engineering Catalytic reaction engineering Clean energy technology ...