JURNAL INTEGRASI PROSES
Vol 13, No 2 (2024)

EFFECT OF CONCENTRATION ON KINETICS AND THERMODYNAMICS PARAMETER IN THE Cu (II) REMOVAL BY ACTIVATED ZEOLITE

Moh. Azhar Afandy (Politeknik Industri Logam Morowali)
Fikrah Dian Indrawati Sawali (Politeknik Industri Logam Morowali)



Article Info

Publish Date
09 Dec 2024

Abstract

Adsorption is a commonly used technique for removing heavy metals, particularly Cu (II), due to its efficiency, cost-effectiveness, simple operation, high stability, and excellent selectivity. This study aims to investigate the impact of varying Cu (II) concentrations on the kinetic and thermodynamic parameters during the adsorption process. The adsorption of Cu (II) by activated zeolite was conducted in several batches, using various initial concentrations (20-120 mg/L) and for varied operating time (30-180 minutes). Various kinetic models have been used to evaluate kinetic rate parameters and maximum adsorption capacity, calculated using linear regression equations. Thermodynamic studies were conducted at different temperatures (303-318 K). The study's results indicate that the concentration has a comparable impact on Cu (II) adsorption by activated zeolite, suggesting a pseudo-second-order equation. As the concentration of Cu (II) increases, so do the adsorption capacity (qe) and adsorption rate. At a Cu (II) concentration of 120 mg/L, the adsorption capacity and rate were the maximum, with qe= 5.6054 mg/g, k2 = 64.2279 g.mg-1.min-1, and Coefficient Correlation value (R2) = 0.9998. The ΔG° value suggests that the adsorption process happens spontaneously and through physical adsorption. On the other hand, the ΔH° value reveals that it happens endothermic.

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Journal Info

Abbrev

JIP

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Description

Jurnal integrasi proses (JIP) diterbitkan oleh Jurusan Teknik Kimia Universitas Sultan Ageng Tirtayasa dua kali dalam setahun. JIP menerima artikel dalam bidang teknik kimia berupa original research papers, reviewed papers dan short communications dari para peneliti, akademisi, industri dan ...