IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)
Vol 9, No 3 (2024): October 2024

Synthesis and Characterization of Schiff Base from 4,4-Diaminodiphenyl Ether and Vanillin and its Interaction with Cu2+ Metal Ion

Hidayati, Nurlisa (Unknown)
Dhamayanti, Erika (Unknown)
Desnelli, Desnelli (Unknown)
Said, Muhammad (Unknown)
Yuliasari, Nova (Unknown)
Nurlailia, Umi (Unknown)



Article Info

Publish Date
25 Oct 2024

Abstract

The Schiff base has synthesized from the reaction between 4,4-diaminodiphenyl ether and vanillin. The resulting Schiff base acts as a ligand and interacts with Cu2+ metal ions to form a complex compound. The Schiff base was analyzed using UV-visible and FT-IR spectroscopy, as well as X-ray diffraction (XRD). The stability of the Schiff base under different pH conditions was investigated, along with the interference effects of Cd2+ and Zn2+ ions on the formation of Schiff base complexes with Cu2+. The formation of a yellow solid crystal indicated the successful synthesis of the Schiff base. The appearance of maximum absorption at 250 nm on the UV-Vis spectra signifies the electronic transition from π to π*. Absorption spectra at 1600 cm-1 indicate the presence of an azomethine group. The diffraction pattern showed a sharp peak at an angle of 2θ= 19.301°, 51.04° for the Schiff base 4,4-diamino diphenyl ether-vanillin. Schiff base compounds exhibit the highest stability at pH 5, where the C=N double bond formed is more stable than other pH. Schiff base ligands form complexes with Cu2+ metal ions, characterized by absorption in the charge transfer region (LMCT) at λ 400 nm and the d-d transition at λ 630 nm. The presence of Cd²⁺ and Zn²⁺ metal ions shifting absorption of the Schiff Base-Cu²⁺ ligand complex towards shorter wavelengths (hypsochromic effect)

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Journal Info

Abbrev

IJFAC

Publisher

Subject

Biochemistry, Genetics & Molecular Biology Chemistry Environmental Science

Description

Indonesian Journal of Fundamental and Applied Chemistry (IJFAC) is an international research journal and invites contributions of original research articles as well as review articles in several areas of chemistry. The journal aims to publish refereed, high-quality research papers with significant ...