JURNAL DINAMIKA VOKASIONAL TEKNIK MESIN
Vol. 9 No. 2 (2024)

ELECTROCHEMICAL PERFORMANCES OF NITROGEN-DOPED CARBON/MNO2 COMPOSITE SUPERCAPACITOR ELECTRODE IN KI-ADDED NA2SO4 ELECTROLYTE

Sutarsis, Sutarsis (Unknown)
Abyan, Demas Muhammad (Unknown)
Kussuma, Fahrul Ardian Firmanda (Unknown)
Pradesar, Yusuf (Unknown)
Purniawan, Agung (Unknown)



Article Info

Publish Date
08 Oct 2024

Abstract

In this study, Nitrogen-doped Activated Carbons (NAC) with different Nitrogen concentrations (NAC1, NAC2, NAC3) and Manganese Dioxide (MnO2) were composited to make the hybrid active material for supercapacitor electrodes to improve the energy density of NAC by adding the pseudo-redox capacitive properties of NAC/MnO2 composite electrode. NAC active material was made from the pyrolyzing biomass carbon and Polyaniline mixture at 800 °C in a nitrogen atmosphere for 2 hours. NAC/MnO2 hybrid material was synthesized by heating NAC: MnO2 with a ratio of 5:1 at 400 °C for 2 hours. Peaks analysis of X-ray diffraction of NAC/MnO2 powder shows that the MnO2 phase was formed as a composite with NAC. The electrochemical performance of the NAC3/MnO2 electrode exhibited the highest capacitance of 168 Fg-1 at a scan rate of 5 mVs-1 in Potassium Iodide (KI)-added Na2SO4 electrolyte. According to the Cycle Voltammetry (CV) measurement, the NAC3/MNO2 composite electrode shows hybrid capacitive behavior consisting of pseudo-redox and double-layer electrostatic energy storage mechanisms in KI-added Na2SO4 electrolyte. NAC3/MnO2 composite electrode demonstrates a high energy density of 22 Whkg-1 at 5 mVs-1.

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Journal Info

Abbrev

dynamika

Publisher

Subject

Education Mechanical Engineering Social Sciences

Description

Jurnal Dinamika Vokasional Teknik Mesin (JDVTM) is published by the Department of Mechanical Engineering Education, Faculty of Engineering, State University of Yogyakarta. The journal is published twice a year in April and October. Each publication contains articles comprising high quality ...