Journal of Batteries for Renewable Energy and Electric Vehicles
Vol. 1 No. 01 (2023): MAY 2023

The Effect of Lithium Excess on NMC-721 using Oxalate Co-precipitation

Revina Dea Nanda (University of Sultan Ageng Tirtayasa)
Sigit Aryo Kristianto (National Battery Research Institute)
Evvy Kartini (National Battery Research Institute)
Muhammad Fakhrudin (National Research and Innovation Agency)



Article Info

Publish Date
15 May 2023

Abstract

Lithium Nickel Manganese Cobalt Oxide (Li-NMC) has been regarded as preferred cathode material for Lithium-ion battery (LIB), compared to other materials such as Lithium Cobalt Oxide (LCO) and Lithium Manganese Oxide (LMO). Ni-rich content displays severe cycling performance and needs to be addressed to improve its performance of electric vehicle. This research focused on synthesis NMC-721 precursors with the oxalate co-precipitation. Furthermore, a variation of lithium hydroxide with the excess of 3% and 5% were added into the precursors, then calcined at temperature 800 ℃ for 12 hours. The product of precursor was analyzed by X-Ray Fluorescence (XRF) and Particle Size Analysis (PSA) to analyze elemental composition and particle size, respectively. Meanwhile, the NMC-721 cathodes were characterized by an X-Ray Diffraction. The XRF data of precursor shows the ratio of transition metals at 7.5:1.5:1 identifying that more Ni content and less Mn content in the NMC-721, due to oxalate co-precipitation. The PSA shows that the average diameter of the precursor was 9.19 ± 0.31 (µm). The XRD result shows that the crystal structure of NMC-721 cathode belongs to hexagonal structure. It can be concluded that the NMC-721 were successfully synthesized and can be applied for lithium-ion battery.

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Journal Info

Abbrev

jbrev

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Electrical & Electronics Engineering Energy Materials Science & Nanotechnology Mechanical Engineering

Description

Aim The JBREV is devoted to publish new and original research, article review related to battery materials, science & engineering that applicable to renewable energy and electric vehicles. Subject Area (1) Battery Materials Science and Engineering, (2) Electric Vehicles, Mechanical, and Electrical ...