Jurnal Teknik Kimia USU
Vol. 14 No. 1 (2025): Jurnal Teknik Kimia USU

Esterifikasi dan Transesterifikasi Minyak Kelapa Sawit Off-grade Menjadi Biodiesel Menggunakan Katalis Barium Hidroksida

Nurfatihayati (Unknown)
Helwani, Zuchra (Unknown)
Bahri, Syaiful (Unknown)



Article Info

Publish Date
27 Mar 2025

Abstract

This research aimed to produce biodiesel from off-grade palm oil using barium hydroxide (Ba(OH)2) catalyst. The free fatty acid (FFA) content in off-grade palm oil is quite high, so the biodiesel production process is carried out in two-stages, i.e. esterification and transesterification. The esterification of off-grade palm oil (500 mL) was carried out at 60 oC for 1 hour, methanol:oil molar ratio of 12:1, stirrer speed of 400 rpm, and 1 wt-% sulfuric acid (H2SO4) as the catalyst. Next, the transesterification process used a methanol:oil molar ratio of 9:1, stirrer speed of 400 rpm, for 2 hours with the variation of temperatures (50, 60, and 70 oC) and Ba(OH)2 catalyst amounts (1, 2 and 3 wt-%). The best result was obtained with 60 oC and Ba(OH)2 catalyst amount 3 wt-%. Based on Gas Chromatography-Mass Spectroscopy (GC-MS) analysis, the best yield of fatty acid methyl ester was 98.97%, with major components being 40.87% palmitic acid and 35.87% oleic acid. The characteristics of biodiesel produced were density of 860.46 kg/m3, viscosity of 4.08 mm/s2, flash point of 145 oC and acid value of 0.457 mg KOH/g biodiesel.

Copyrights © 2025