Heca Journal of Applied Sciences
Vol. 3 No. 1 (2025): March 2025

Enhancing TiO2 Photoelectrode Performance: The Role of La Doping Using the Sol-Gel Process

Jannah, Mifthahul (Unknown)
Azmi, Nurul (Unknown)
Lala, Andi (Unknown)
Jalil, Zulkarnain (Unknown)
Mursal, Mursal (Unknown)



Article Info

Publish Date
24 Mar 2025

Abstract

Due to growing interest in renewable energy technologies, dye-sensitized solar cells (DSSCs) have emerged as promising alternatives to conventional photovoltaics. This study explores the enhancement of titanium dioxide (TiO2) photoelectrodes through doping with lanthanum (La), a rare earth element known for its ability to modify semiconductors' structural and electronic properties. La-doped TiO2 was synthesized using the sol-gel method with La concentrations ranging from 0 to 4 mol%. The resulting films were deposited onto substrates and sintered at 600 °C for 1 hour. Characterization techniques included X-ray diffraction (XRD), scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS), UV-Vis spectrophotometry, and Fourier-transform infrared spectroscopy (FTIR). XRD confirmed the anatase phase of TiO2 and the appearance of La2O₃ phases with doping. The smallest crystallite size (8.20 nm) and lowest bandgap energy (3.31 eV) were achieved at 1 mol% La, compared to 3.52 eV for undoped TiO2. SEM-EDS indicated uniform La distribution, while FTIR revealed changes in surface chemistry. These results suggest that La doping, particularly at 1 mol%, can effectively enhance the optical and structural properties of TiO2, making it a promising candidate for improved DSSC performance.

Copyrights © 2025






Journal Info

Abbrev

hjas

Publisher

Subject

Agriculture, Biological Sciences & Forestry Earth & Planetary Sciences Engineering Health Professions Medicine & Pharmacology

Description

Heca Journal of Applied Sciences is a premier international scientific journal that publishes high quality original research articles, review articles, and case reports in the field of applied sciences. The journal mission is to encourage interdisciplinary research, promote knowledge sharing, and ...