INDONESIAN JOURNAL OF URBAN AND ENVIRONMENTAL TECHNOLOGY
VOLUME 8, NUMBER 1, APRIL 2025

SUSTAINABLE NICKEL RECOVERY FROM NICKEL SLAG WASTE USING DIETHYLAMINE DITHIOCARBAMATE: ENHANCING RESOURCE EFFICIENCY AND MINIMIZING ENVIRONMENTAL IMPACT

Fadliah Fadliah (Department of Chemistry, Faculty of Mathematics, and Natural Science, Hasanuddin University Makassar, Makassar, South Sulawesi, Indonesia)
Muhammad Burhannudinnur (Department of Geological Engineering, Faculty of Earth and Energy Technology, Universitas Trisakti, Jakarta, Indonesia)
Paulina Taba (Department of Chemistry, Faculty of Mathematics, and Natural Science, Hasanuddin University Makassar, Makassar, South Sulawesi, Indonesia)
Abdul Wahid Wahab (Department of Chemistry, Faculty of Mathematics, and Natural Science, Hasanuddin University Makassar, Makassar, South Sulawesi, Indonesia)
Syahruddin Kasim (Department of Chemistry, Faculty of Mathematics, and Natural Science, Hasanuddin University Makassar, Makassar, South Sulawesi, Indonesia)
Abdul Karim (Department of Chemistry, Faculty of Mathematics, and Natural Science, Hasanuddin University Makassar, Makassar, South Sulawesi, Indonesia)
Hasri Hasri (Department of Chemistry, Universitas Negeri Makassar, Makassar, South Sulawesi, Indonesia)
Subandrio (Department of Mining Engineering, Faculty of Earth and Energy Technology, Universitas Trisakti, Jakarta, Indonesia)
Tri Widayati Putri (Department of Fishery Technology, Institute of Technology and Business Maritime Balik Diwa, Makassar, South Sulawesi, Indonesia)
Arfiani Nur (Department of Chemistry, Faculty of Science and Technology, Universitas Islam Negeri Alauddin Makassar, Makassar, South Sulawesi, Indonesia)
Ghanima Yasmaniar (Department of Petroleum Engineering, Faculty of Earth and Energy Technology, Universitas Trisakti, Jakarta, Indonesia)
Ridha Husla (Department of Petroleum Engineering, Faculty of Earth and Energy Technology, Universitas Trisakti, Jakarta, Indonesia)
Sulistiani Jarre (Department of Chemistry, Faculty of Mathematics, and Natural Science, Hasanuddin University Makassar, Makassar, South Sulawesi, Indonesia)
Audrey Zahra (Department of Forest Product, Chungbuk National University Graduate School, Chungbuk, South Korea)
Eid Abdalrazaq (Department of Chemistry, Faculty of Science, Al Hussein Bin Talal University, Ma’an, Jordan)
Shivaa Prasad Kollur (School of Physical Sciences, Amrita Vishwa Vidyapeetham, Mysuru Campus, Mysuru, Karnataka, India)
Indah Raya (Department of Chemistry, Faculty of Mathematics, and Natural Science, Hasanuddin University Makassar, Makassar, South Sulawesi, Indonesia)



Article Info

Publish Date
27 Apr 2025

Abstract

Slag waste from the metal refining industry, if left to accumulate for a long time, can become a source of environmental pollution due to the content of heavy metals that can dissolve and spread to the surrounding environment. However, slag can also be an alternative source for obtaining valuable metals. Aim: This study aims to examine the ability of diethylaminedithiocarbamate ligands to recover nickel metal from slag waste through the mechanism of complex compound formation. Methodology and results: The extraction process was carried out at the optimal pH for each ligand to maximize the selectivity and efficiency of metal recovery. Characterization of the complex compounds from the reaction was carried out using various analytical techniques, including Fourier Transform Infrared Spectroscopy (FTIR), UV-visible spectroscopy (UV-Vis), X-Ray Diffraction (XRD), Scanning Electron Microscopy with Energy Dispersive X-ray Spectroscopy (SEM-EDS), and melting point tests to determine the thermal stability of the compound. The study results indicate that diethylaminedithiocarbamate ligands can selectively form complex compounds with nickel metal in slag and are effective in recovering metals from slag waste with a recovery value of 94.88%. Conclusion, significance, and impact study: The results of this study indicate that using diethylaminedithiocarbamate ligands can be an environmentally friendly approach to using slag waste as a secondary source of metals.

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Journal Info

Abbrev

urbanenvirotech

Publisher

Subject

Agriculture, Biological Sciences & Forestry Chemical Engineering, Chemistry & Bioengineering Civil Engineering, Building, Construction & Architecture Energy Environmental Science

Description

The scope of the journal emphasis not limited to urban environmental management and environmental technology for case study in Indonesia and for other region in the world as well. Urban Environmental Management: environmental modeling, cleaner production, waste minimization and management, energy ...