Indonesian Journal of Chemistry
Vol 25, No 4 (2025)

Kinetic Insights into Cadmium and Lead Removal Using Cellulose-Based Schiff Base Complexes as Adsorbents

Ibrahim, Farah Muaiad (Unknown)



Article Info

Publish Date
31 Jul 2025

Abstract

The removal of heavy metals from water is a key environmental challenge. This study focuses on synthesizing and using Schiff base-modified cellulose as adsorbents for cadmium (Cd) and lead (Pb) ions. The materials were developed by modifying cellulose and incorporating Schiff base ligands with Fe(III) and Zn(II) binding sites (Schiffs 1 and 2). Characterization through EDX, SEM, FTIR, elemental analysis, XRD, and TGA confirmed improved surface properties and active adsorption sites. Adsorption followed pseudo-second-order kinetics, indicating chemisorption. The monolayer adsorption capacities for Schiff 1 were 83 mg/g Cd and 78 mg/g Pb, while for Schiff 2, they were 70 mg/g Cd and 63 mg/g Pb. Optimal conditions included solution pH 4.0–5.0, stirring for 45–60 min, 100 mg/L metal concentration, and room temperature (25 ± 2 °C). EDTA efficiently desorbed Cd and Pb for 4 cycles with over 85% efficiency. This study highlights the material’s potential as a cost-effective and eco-friendly solution for wastewater treatment.

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Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...