Journal of Multidisciplinary Applied Natural Science
Articles in Press

Preparation and Characterization of Cellulose-clay Composite using Indonesian Natural Bentonite for Cr(VI) Adsorption

Julinawati, Julinawati (Unknown)
Nadia, Eka (Unknown)
Mustafa, Irfan (Unknown)
Suryati, Suryati (Unknown)



Article Info

Publish Date
06 Aug 2025

Abstract

Contamination of Cr(VI) is of global concern, whereas the innovation in wastewater treatment is required. Combination of bentonite and cellulose could produce an effective adsorbent to treat Cr(VI)-containing wastewater. The aim of this study was to investigate the use of composite bentonite/cellulose (B/Cell) to remove Cr(VI) in the aqueous media, in which the bentonite was collected from local sources. The Na-bentonite was firstly prepared before proceeding to cellulose embedment. The resultant B/Cell was characterized for its functional groups, morphology, and crystallinity. The Cr(VI) adsorption capacity and removal efficiency were determined based on batch adsorption. Our findings revealed that the B/Cell composite with a 4:1 bentonite-to-cellulose mass ratio exhibited the highest removal efficiency (85.68%) among tested formulations. Fourier-transform infrared spectroscopy, scanning electron microscopy, and X-ray diffraction analyses confirmed the successful integration of cellulose and structural modification of bentonite. Optimal adsorption was achieved at pH 3, 180-min contact time, and 10 g/L adsorbent dosage. Isotherm modeling showed excellent fits for Sips (R2 = 0.9992) model, with maximum adsorption capacity reaching 192.56 mg/g. Kinetic analysis indicated pseudo-second-order kinetics (R2 = 0.959, qe = 1.018 mg/g), suggesting a chemisorption mechanism. These results highlight the potential of the B/Cell composite as an efficient and low-cost adsorbent for Cr(VI) removal from aqueous environments.

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Journal Info

Abbrev

jmans

Publisher

Subject

Agriculture, Biological Sciences & Forestry Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Energy Environmental Science Immunology & microbiology Materials Science & Nanotechnology Mathematics Physics

Description

Journal of Multidisciplinary Applied Natural Science (abbreviated as J. Multidiscip. Appl. Nat. Sci.) is a double-blind peer-reviewed journal for multidisciplinary research activity on natural sciences and their application on daily life. This journal aims to make significant contributions to ...