EduChemia: Jurnal Kimia dan Pendidikan
Vol 10, No 1 (2025)

Smart-Coating Corrosion Inhibitor for Carbon Steel Using LDH Modified with Laundry Detergent Waste

Irmayanti, Dwi (Surabaya State University)
Jamilah, Badrotul (Surabaya State University)
Agustin, Ardianti Dwi (Surabaya State University)
Fitria, Maulida Rizki (Surabaya State University)
Wijayanto, Herry (Unknown)



Article Info

Publish Date
08 Aug 2025

Abstract

This research was conducted with the aim of reducing environmentally harmful detergent waste while utilizing its anionic surfactant content for the development of Zn-Al LDH composites with benzimidazole as a smart corrosion inhibitor for low-carbon steel, providing dual protection. The samples used in this research included detergent waste collected from commercial laundry services in the Ketintang area of Surabaya, commercial detergent, dodecylbenzenesulfonate, and pure Zn-Al LDH. The methodology involves the synthesis of Zn-Al LDH followed by characterization using FTIR, XRD, and TGA. The results indicate that the thermal decomposition profiles of Zn-Al LDH intercalated with commercial detergent, detergent waste, and dodecylbenzenesulfonate confirm that Zn-Al LDH can be modified with laundry waste. Additionally, interactions between Zn-Al LDH and benzimidazole enhance the crystalline structure of Zn-Al LDH, improving its quality as an anticorrosion material. Quantitative corrosion rate analysis using the weight loss method revealed that the Zn-Al LDH–dodecylbenzenesulfonate–benzimidazole sample exhibited the highest corrosion resistance, followed by the Zn-Al LDH–commercial detergent–benzimidazole, Zn-Al LDH–pure–benzimidazole, and Zn-Al LDH–detergent waste–benzimidazole samples. Overall, these findings support the feasibility of repurposing detergent waste as a functional additive for Zn-Al LDH-based corrosion inhibitors. Although not as effective as pure commercial surfactants, detergent waste provides environmental and functional benefits, reducing environmentally harmful and sustainable smart coatings for corrosion protection.

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Journal Info

Abbrev

EduChemia

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry Education Materials Science & Nanotechnology

Description

Focus and Scope Educhemia (Jurnal Kimia dan Pendidikan) is Periodicals published the results of research related to the development of science and technology in the field of Chemistry and Chemistry education as a form of intellectual property Chemistry: Organic chemistry, Inorganic chemistry, ...