Analit: Analytical And Environmental Chemistry
Vol. 9, No. 01 April (2024) Analit : Analytical and Environmental Chemistry

SYNTHESIS OF CHITOSAN FROM KIJING SHELLS (P. exilis) WITH THE ADDITION OF CHLOROACETIC ACID AND TRIPOLYPHOSPHATE CROSS-LINKER FOR Cu (II) METAL ADSORPTION

khairia, ihdal (Unknown)
Hasri, Hasri (Unknown)
Majid, Ahmad Fudhail (Unknown)



Article Info

Publish Date
30 Apr 2024

Abstract

The utilization of kijing clam shells as raw materials for chitosan production is one of the efforts to reduce kijing clam shell waste. This study is an experiment aimed at determining how to synthesize carboxymethyl chitosan (CM-Ch) and carboxymethyl chitosan-tripolyphosphate (CM-Ch-TPP), as well as the influence of pH and concentration of CM-Ch and CM-Ch-TPP on the adsorption of Cu(II) metal ions. The results showed that chitosan had a degree of deacetylation (DD) of 76%. Synthesized CM-Ch had characteristic functional groups at peaks 1610.56 cm-1 and 1425.4 cm-1. In the synthesized CM-Ch-TPP, there were functional groups at the peak of P=O stretch vibration and P-O stretch vibration at wave numbers 1213.23 cm-1 and 11,53.43 cm-1 in kijing. It is concluded that CM-Ch and CM-Ch-TPP have the ability to adsorb Cu(II) metal ions at pH 10 with concentrations ranging from 50 to 150 ppm.     The utilization of kijing clam shells as raw materials for chitosan production is one of the efforts to reduce kijing clam shell waste. This study is an experiment aimed at determining how to synthesize carboxymethyl chitosan (CM-Ch) and carboxymethyl chitosan-tripolyphosphate (CM-Ch-TPP), as well as the influence of pH and concentration of CM-Ch and CM-Ch-TPP on the adsorption of Cu(II) metal ions. The results showed that chitosan had a degree of deacetylation (DD) of 76%. Synthesized CM-Ch had characteristic functional groups at peaks 1610.56 cm-1 and 1425.4 cm-1. In the synthesized CM-Ch-TPP, there were functional groups at the peak of P=O stretch vibration and P-O stretch vibration at wave numbers 1213.23 cm-1 and 11,53.43 cm-1 in kijing. It is concluded that CM-Ch and CM-Ch-TPP have the ability to adsorb Cu(II) metal ions at pH 10 with concentrations ranging from 50 to 150 ppm.  

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Journal Info

Abbrev

analit

Publisher

Subject

Chemistry Energy Environmental Science

Description

Analit is a scientific journal that contains research results and reviews in the field of analytics and the environment. Fields of research studies or review articles that can be published in this journal include analytical chemistry, biosensor, chemical sensor, synthesis and characterization of ...