Jurnal Sains Materi Indonesia
Vol. 27 No. 2 (2026): Jurnal Sains Materi Indonesia

The Influence of pH on Structural, Morphological, and Optical Properties of Al2O3 Nanoparticles Synthesized by Syzygium aromaticum Leaf Extract

Anggara Budi Susial (Department of Physics, Universitas Negeri Jakarta)
Natasya Frysillia Wardani (Department of Physics, Universitas Negeri Jakarta)
Rahmat Setiawan Mohar (National Research and Innovation Agency, Indonesia)
Nurfina Yudasari (National Research and Innovation Agency, Indonesia)
Artoto Arkundato (University of Jember, Indonesia)
Haris Suhendar (Universitas Negeri Jakarta)
Hadi Nasbey (Department of Physics Education, Universitas Negeri Jakarta)
Imam Basori (Department of Mechanical Engginering, Universitas Negeri Jakarta)
Tan Swee Tiam (Xiamen University of Malaysia)
Iwan Sugihartono (Department of Physics, Universitas Negeri Jakarta)



Article Info

Publish Date
31 Jan 2026

Abstract

Aluminum oxide (Al2O3) nanoparticles have been synthesized through a biosynthesis approach, employing Syzygium aromaticum leaf extracts prepared under varying acidic conditions as bioreductants in the reaction with aluminum nitrate nanohydrate. The Al2O3 nanoparticles were annealed at 450 °C for one hour to facilitate the formation. Then, the samples were characterized for their crystal structure, morphology, and optical properties using X-ray diffraction (XRD), scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDX), and UV-visible (UV-Vis) spectrophotometry, respectively. XRD analysis confirmed that the Al2O3 nanoparticles possess an orthorhombic crystal structure, corresponding to Inorganic Crystal Structure Database (ICSD) entry #98-009-4485. The average crystallite sizes were measured to be 37.36 nm, 15.47 nm, and 12.52 nm for nanoparticles synthesized at pH-9, pH-10, and pH-11, respectively. Morphologically, the pH condition affects the morphology of Al2O3 nanoparticles. The reflectance spectrum peak of Al2O3 nanoparticles in the wavelength range of 328–336 nm is observed with the band gap energy of 2.92-3.01 eV. According to these results, it is believed that the Al2O3 nanoparticles have potential applications as photocatalysts.

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Journal Info

Abbrev

jsmi

Publisher

Subject

Engineering Industrial & Manufacturing Engineering Materials Science & Nanotechnology

Description

Jurnal Sains Materi Indonesia (Indonesian Journal of Materials Science, JUSAMI) is an international peer-reviewed journal that publishes significant and important research from all areas of materials science and engineering. The topics discussed in JUSAMI are research & development results in ...